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Poly(butylene terephthalate)

Poly(butylene terephthalate) Suppliers list
Company Name: Dongguan Zhenge New Material Technology Co., Ltd.  Gold
Tel: 13650015200 13650015200
Email: 184807813@qq.com
Company Name: Beijing HuaMeiHuLiBiological Chemical   
Tel: 010-56205725
Email: waley188@sohu.com
Company Name: Shanghai Macklin Biochemical Co.,Ltd.  
Tel: 15221275939 15221275939
Email: shenlinxing@macklin.cn
Company Name: Shanghai YuanYe Biotechnology Co., Ltd.  
Tel: 18916372613
Email: yanzihan@shyuanye.com
Company Name: Shenzhen Sendi Biological Technology Co., Ltd.  
Tel: 18124570582 TEL:0755-23574479 2355327139
Email: siliao02@yccreate.com

Poly(butylene terephthalate) manufacturers

Poly(butylene terephthalate) Basic information
Product Name:Poly(butylene terephthalate)
Synonyms:terephthalicacid-tetramethyleneglycolpolymer;tetramethylenediol-terephthalicacidpolymer;tetramethyleneglycol-terephthalicacidpolymer;Thermocomp WC-1006;Ultradur B 2550;Ultradur B 4300 G10;Ultradur B 4500;Ultradur KR 4001
CAS:26062-94-2
MF:C12H16O6
MW:256.25
EINECS:607-857-5
Product Categories:
Mol File:26062-94-2.mol
Poly(butylene terephthalate) Structure
Poly(butylene terephthalate) Chemical Properties
Melting point 226 °C
density 1.31 g/mL at 25 °C(lit.)
storage temp. -70°C
form pellets
biological sourcehuman
Specific Activity6-8nmol/min·mg
Cosmetics Ingredients FunctionsVISCOSITY CONTROLLING
FILM FORMING
InChIInChI=1S/C8H6O4.C4H10O2/c9-7(10)5-1-2-6(4-3-5)8(11)12;5-3-1-2-4-6/h1-4H,(H,9,10)(H,11,12);5-6H,1-4H2
InChIKeyPCVVBHUFWPHCAL-UHFFFAOYSA-N
SMILESC(C1C=CC(C(=O)O)=CC=1)(=O)O.C(CO)CCO
CAS DataBase Reference26062-94-2
EPA Substance Registry SystemTerephthalic acid 1,4-butanediol polymer (26062-94-2)
Safety Information
WGK Germany 3
TSCA TSCA listed
Storage Class11 - Combustible Solids
Hazardous Substances Data26062-94-2(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
Poly(butylene terephthalate) Usage And Synthesis
Description Polybutylene terphthalate (PBT; Poly(butylene terephthalate)) is a semicrystalline thermoplastic polyester considered as a medium performance engineering polymer. It is produced industrially in a two-step batch or continuous process. The first step involves the transesterification of dimethyl terephthalate (DMT) with 1,4-butanediol (BDO) to produce hydrobutyl terephtlate (bis-HBT) at a temperature of 200°C. The second step consists to the polycondensation of bis-HBT at 250°C to yield PBT. It exhibits both excellent electrical properties and chemical resistance. When reinforced with glass fibers, it has improved stiffness and mechanical strength. Typical uses include connectors, capacitors and cable enclosures. PBT is also used in hot appliances such as iron and kettles.
Chemical PropertiesPoly(butylene terephthalate) is prepared in a condensation reaction between dimethyl terephthalate and 1,4-butanediol and its repeating unit has the general structure:
Poly(butylene terephthalate) structure
This thermoplastic shows good tensile strength, toughness, low water absorption, and good frictional properties, plus good chemical resistance and electrical properties.
UsesPolybutylene terephthalate (PBT) resin is widely used in the automotive, electronics, electrical, machinery, and instrumentation industries to manufacture various structural parts and components. It is also used to produce filaments and films. Glass fiber reinforced PBT with added flame retardants is extensively used in flame-retardant components for televisions, such as output transformer frames and bases, various electrical connectors and switches, potentiometers, strip connectors, and color picture tube sockets. PBT can be blended with other polymers to create plastic alloys, with the largest market being the automotive industry, such as for car bumpers and ignition components. These alloys are also increasingly being used in the food industry, for example, to create microwave oven heating containers that can withstand temperatures above 160°C. Additionally, it is used in mechanical parts and fiber modification.
Synthesis

PBT preparation methods are: dimethyl terephthalate and 1,4-butanediol as raw materials for the ester-exchange method; high purity terephthalic acid and 1,4-butanediol as raw materials for the direct esterification method. The former is generally used in the industry, firstly, the ester exchange reaction is carried out in the ester exchange reactor at atmospheric pressure and 160-190, and then the polycondensation reaction is carried out at pressurized and elevated temperature. The continuous method process can be used to produce low, medium and high products with different viscosities.

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