六[I-(2-氨基-1,4-苯二甲酸基)][四-羟基辛-1-氧代辛钛],NH2-MIL-125(TI),AYRSORBT125
| 中文名称 | 六[I-(2-氨基-1,4-苯二甲酸基)][四-羟基辛-1-氧代辛钛],NH2-MIL-125(TI),AYRSORBT125 |
|---|---|
| 中文同义词 | 六[I-(2-氨基-1,4-苯二甲酸基)][四-羟基辛-1-氧代辛钛],NH2-MIL-125(TI),AYRSORBT125;NH2-MIL-125(TI)金属有机骨架;六[Μ-[2-氨基-1,4-苯二甲酸(2-)-ΚO1:ΚO′1]]四-Μ-羟基八-Μ-氧代八钛环;六[Μ-[2-氨基-1,4-苯二甲酸(2-)-ΚO1:ΚO′1]]四-Μ-羟基八-Μ-氧代八钛 CYCLO;六聚[Μ-(2-氨基-1,4-苯二甲酸)][四-Μ-羟基-八-Μ-羰基八钛],NH2-MIL-125(TI) |
| 英文名称 | Hexakis[μ-(2-amino-1,4-benzenedicarboxylato)][tetra-μ-hydroxyocta-μ-oxooctatitanium], NH2-MIL-125(Ti), CONEKTIC(TM) T125 |
| 英文同义词 | HEXAKIS[Μ-(2-AMINO-1,4-BENZENEDICARBOXYLATO)][TETRA-Μ-HYDROXYOCTA-Μ-OXOOCTATITANIUM],NH2-MIL-125(TI),CONEKTIC T125;Hexakis[μ-(2-amino-1,4-benzenedicarboxylato)][tetra-μ-hydroxyocta-μ-oxooctatitanium], NH2-MIL-125(Ti), CONEKTIC(TM) T125;MIL-125(Ti)-NH;Hexakis[μ-(2-amino-1,4-benzenedicarboxylato)][tetra-μ-hydroxyocta-μ-oxooctatitanium], NH2-MIL-125(Ti), AYRSORB T125;MIL-125(Ti)-NH2;Hexakis[mu-(2-amino-1,4-benzenedicarboxylato)][tetra-mu-hydroxyocta-mu-oxooctatitanium], NH2-MIL-125(Ti), AYRSORB? T125;Hexakis[μ-[2-amino-1,4-benzenedicarboxylato(2-)-κO1:κO′1]]tetra-μ-hydroxyocta-μ-oxooctatitanium cyclo;MIL-125-NH2(Ti) |
| CAS号 | 1309760-94-8 |
| 分子式 | C48H30N6O36Ti8 |
| 分子量 | 1649.71 |
| EINECS号 | |
| 相关类别 | MOF |
| Mol文件 | 1309760-94-8.mol |
| 结构式 | ![六[I-(2-氨基-1,4-苯二甲酸基)][四-羟基辛-1-氧代辛钛],NH2-MIL-125(TI),AYRSORBT125 结构式](CAS/20211123/GIF/1309760-94-8.gif) |
六[I-(2-氨基-1,4-苯二甲酸基)][四-羟基辛-1-氧代辛钛],NH2-MIL-125(TI),AYRSORBT125 性质
| 形态 | 粉末 |
|---|---|
| 颜色 | 粘黄色 |
| InChI | InChI=1S/6C8H7NO4.12O.8Ti/c6*9-6-3-4(7(10)11)1-2-5(6)8(12)13;;;;;;;;;;;;;;;;;;;;/h6*1-3H,9H2,(H,10,11)(H,12,13);;;;;;;;;;;;;;;;;;;;/q;;;;;;8*-2;4*-1;8*+4/p-12 |
| InChIKey | LEXJUXLCURDDMR-UHFFFAOYSA-B |
| CAS 数据库 | 1309760-94-8 |
| 配位金属 | Ti |
| 配体 | 2-氨基对苯二酸（CAS：10312-55-7） |
| 孔径 | 0.6nm*0.8nm |
| 粒径 | 500nm-1umroundparticles |
| 比表面 | BET比表面1100-1200m2/g |
参考文献
[1] A New Photoactive Crystalline Highly Porous Titanium(IV) Dicarboxylate. https://doi.org/10.1021/ja903726m
[2] Facile synthesis of amino-functionalized titanium metal–organic frameworks and their superior visible-light photocatalytic activity for Cr(VI) reduction. https://doi.org/10.1016/j.jhazmat.2014.11.039
[3] Design and syntheses of MOF/COF hybrid materials via postsynthetic covalent modification: An efficient strategy to boost the visible-light-driven photocatalytic performance. https://doi.org/10.1016/j.apcatb.2018.10.043
[4] An Amine-Functionalized Titanium Metal–Organic Framework Photocatalyst with Visible-Light-Induced Activity for CO₂ Reduction. https://doi.org/10.1002/anie.201108357
[5] Two-Phase System Utilizing Hydrophobic Metal–Organic Frameworks (MOFs) for Photocatalytic Synthesis of Hydrogen Peroxide. https://doi.org/10.1002/anie.201901961