Diethyl cyclopropylmethyl phosphonate

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Company Name: Shanghai Hanhong Scientific Co.,Ltd.  
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Diethyl cyclopropylmethyl phosphonate Basic information
Product Name:Diethyl cyclopropylmethyl phosphonate
Synonyms:diethoxyphosphorylmethylcyclopropane;Phosphonic acid, P-(cyclopropylmethyl)-, diethyl ester;Cyclopropylmethyl ethyl ethylphosphonate;Diethyl P-(cyclopropylmethyl)phosphonate
CAS:863975-37-5
MF:C8H17O3P
MW:192.19
EINECS:
Product Categories:C-C Bond Formation;Horner-Wadsworth-Emmons Reagents;Olefination
Mol File:863975-37-5.mol
Diethyl cyclopropylmethyl phosphonate Structure
Diethyl cyclopropylmethyl phosphonate Chemical Properties
Boiling point 60 °C/0.125 mmHg (lit.)
density 1.023 g/mL at 25 °C (lit.)
refractive index n20/D 1.4380(lit.)
Fp 102 °C
form solid
InChI1S/C8H17O3P/c1-3-10-12(9,11-4-2)7-8-5-6-8/h8H,3-7H2,1-2H3
InChIKeySEZHIFQWGROIOQ-UHFFFAOYSA-N
SMILESCCOP(=O)(CC1CC1)OCC
Safety Information
Safety Statements 23-24/25
WGK Germany 3
Storage Class8A - Combustible corrosive hazardous materials
Hazard ClassificationsAcute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Skin Corr. 1B
MSDS Information
Diethyl cyclopropylmethyl phosphonate Usage And Synthesis
UsesReactant for:
  • Preparation of alkyldichlorophosphine via chlorination reaction under mild conditions

Structural characteristics:
  • Intramolecular hydrogen binding via "banana" bonds between a H atom belonging to the phosphino group and the edge of the cyclopropyl ring
reaction suitabilityreaction type: C-C Bond Formation
Diethyl cyclopropylmethyl phosphonate Preparation Products And Raw materials
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