(4-Methoxyphenyl)dimethylsilanol

Request For Quotation
(4-Methoxyphenyl)dimethylsilanol Suppliers list
Company Name: Shanghai Hanhong Scientific Co.,Ltd.  
Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Company Name: Sigma-Aldrich  
Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Company Name: Meng Cheng Technology (Shanghai) Co., LTD  
Tel: 400-820-6829
Email: sales@mitachieve.com
Company Name: Energy Chemical  
Tel: 400-0056266
Email: marketing1@energy-chemical.com
Company Name: Zhuhai Aobokai Biomedical Technology Co., Ltd.  
Tel: 400-0628126
Email: sales-team@aobchem.com.cn
(4-Methoxyphenyl)dimethylsilanol Basic information
Product Name:(4-Methoxyphenyl)dimethylsilanol
Synonyms:(4-METHOXYPHENYL)DIMETHYLSILANOL;Silanol, 1-(4-methoxyphenyl)-1,1-dimethyl-;(4-Methoxyphenyl)dimethylsilanol 96%
CAS:22868-26-4
MF:C9H14O2Si
MW:182.29
EINECS:
Product Categories:Chemical Synthesis;Organometallic Reagents;Organosilicon;Silanols
Mol File:22868-26-4.mol
(4-Methoxyphenyl)dimethylsilanol Structure
(4-Methoxyphenyl)dimethylsilanol Chemical Properties
Boiling point 82 °C(Press: 0.004 Torr)
density 1.101 g/mL at 25 °C
refractive index n 20/D 1.522
Fp 110 °C
storage temp. 2-8°C
pka14.49±0.53(Predicted)
InChI1S/C9H14O2Si/c1-11-8-4-6-9(7-5-8)12(2,3)10/h4-7,10H,1-3H3
InChIKeyDDLYKNBMTGBOQY-UHFFFAOYSA-N
SMILESCOc1ccc(cc1)[Si](C)(C)O
Safety Information
WGK Germany 3
Storage Class10 - Combustible liquids
MSDS Information
(4-Methoxyphenyl)dimethylsilanol Usage And Synthesis
Uses(4-Methoxyphenyl)dimethylsilanol is a useful silicon nucleophile for Pd-catalyzed cross-coupling.
Uses(4-Methoxyphenyl)dimethylsilanol can be used:
  • As a starting material in the Pd-catalyzed cross-coupling reactions with various aryl halides to obtain biaryl compounds using Cs2CO3 base.
  • As a starting material to prepare potassium (4-methoxyphenyl)dimethylsilanolate, which in turn is used to synthesize biaryl derivatives by reacting with aryl bromides.
  • As a co-catalyst along with Mo(CO)6 applicable in the 4-decyne metathesis.

(4-Methoxyphenyl)dimethylsilanol Preparation Products And Raw materials
Tag:(4-Methoxyphenyl)dimethylsilanol(22868-26-4) Related Product Information
hydroxytrimethylsilane Sodium dimethyl(4-methoxyphenyl)silanolate Methoxy(4-methoxyphenyl)dimethylsilane 1,3-Bis(4-methoxyphenyl)-1,1,3,3-tetramethyldisiloxane, 97% 4,4'-Bis(dimethylhydroxysilyl)diphenyl ether (4-Methoxyphenyl)dimethylsilanol