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Potassium hydrogen phthalate

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Potassium hydrogen phthalate Basic information
Product Name:Potassium hydrogen phthalate
Synonyms:Potassium hydrogen phthalate, reagent ACS, acidimetric standard;POTASSIUM ACID PHTHALATE BIO-REFINED;potassium hydrogen phthalate, primary standard, acs;POTASSIUMBIPHTHALATE,BIOTECHGRADE;POTASSIUMBIPHTHALATE,CRYSTAL,REAGENTSPECIAL,ACS;POTASSIUMBIPHTHALATE,ULTRAPURE;SODIUM AMYL XANTHTATE;POTASSIUM ACID PHTHALATE PRIMARY STANDARD (ACS)
CAS:877-24-7
MF:C8H5KO4
MW:204.22
EINECS:212-889-4
Product Categories:Analytical reagent;Classes of Metal Compounds;K (Potassium) Compounds (excluding simple potassium salts);Typical Metal Compounds;INORGANIC & ORGANIC CHEMICALS
Mol File:877-24-7.mol
Potassium hydrogen phthalate Structure
Potassium hydrogen phthalate Chemical Properties
Melting point 295-300 °C (dec.) (lit.)
Boiling point 98.5-99.5 ;°C/740 ;mmHg(lit .)
density 1.006 g/mL at 20 °C
bulk density900kg/m3
storage temp. Store at +5°C to +30°C.
solubility H2O: 100 mg/mL, clear, colorless
form Solid
color White
OdorOdorless
PH Range3.8 - 4.0 (5% aq. sol.)
PH4.00-4.02 (25.0℃±0.2℃, 0.05M)
Water Solubility 80 G/L (20 ºC)
Merck 14,7612
BRN 3637128
Stability:Stable. Incompatible with strong oxidizing agents.
Cosmetics Ingredients FunctionsBUFFERING
InChI1S/C8H6O4.K/c9-7(10)5-3-1-2-4-6(5)8(11)12;/h1-4H,(H,9,10)(H,11,12);/q;+1/p-1
InChIKeyIWZKICVEHNUQTL-UHFFFAOYSA-M
SMILES[K+].OC(=O)c1ccccc1C([O-])=O
LogP-2.73
CAS DataBase Reference877-24-7(CAS DataBase Reference)
EPA Substance Registry SystemMonopotassium phthalate (877-24-7)
Absorptioncut-off at 309nm in H2O at 0.1M
Safety Information
Hazard Codes Xi,C,T
Risk Statements 36/38-36/37/38-34-61-60
Safety Statements 26-36-24/25-22-45-36/37/39-53
RIDADR UN 1789 8/PG 3
WGK Germany 1
RTECS CZ4326000
F 34
TSCA TSCA listed
HS Code 29173990
Storage Class13 - Non Combustible Solids
ToxicityLD50 orally in Rabbit: > 3200 mg/kg
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Potassium hydrogen phthalate Usage And Synthesis
Chemical Propertieswhite crystalline powder
UsesAs primary standard for preparing volumetric alkali solutions, also as a buffer in pH determinations.
UsesAs a primary standard for preparing volumetric alkali solutions and as a buffer in pH determinations. Potassium hydrogen phthalate is used as a primary standard for acid- base titrations as well as for calibrating pH meters. It acts as a buffer in pH determination. It finds application as a useful standard for total organic carbon testing.
UsesPotassium hydrogen phthalate [KHP; pH(S) = 4.005 (25 °C)] is a certified secondary standard reference material used as a calibration buffer standard for pH instruments or pH electrodes.
General DescriptionSRM 2185_cert SRM 2185 _SDS
Flammability and ExplosibilityNot classified
Purification MethodsCrystallise it first from a dilute aqueous solution of K2CO3, then H2O (3mL/g) between 100o and 0o. Before being used as a standard in volumetric analysis, analytical grade potassium hydrogen phthalate should be dried at 120o for 2hours, then allowed to cool in a desiccator. [Beilstein 9 IV 3169.]
Potassium hydrogen phthalate Preparation Products And Raw materials
Raw materialsPotassium hydroxide-->Phthalic anhydride
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