4-(Ethoxycarbonyl)phenylzinc iodide

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4-(Ethoxycarbonyl)phenylzinc iodide Basic information
Product Name:4-(Ethoxycarbonyl)phenylzinc iodide
Synonyms:4-(ETHOXYCARBONYL)PHENYLZINC IODIDE, 0.5 M SOLUTION IN TETRAHYDROFURAN;4-(ethoxycarbonyl)phenylzinc iodide solution;4-(Iodozincio)benzoic acid ethyl ester;Ethyl 4-(iodozincio)benzoate;4-(Ethoxycarbonyl)phenylzinc iodide, Packaged under Argon in resealable ChemSeal? bottles;4-(Ethoxycarbonyl)phenylzinc iodide solution 0.5M in THF;4-(Ethoxycarbonyl)phenylzinc iodide solution 0.5 in THF;4-(Ethoxycarbonyl)butylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal&trade
CAS:131379-16-3
MF:C9H9IO2Zn
MW:341.46
EINECS:
Product Categories:Aryl;Organozinc Halides;Reike and Organozinc Reagents;Chemical Synthesis;Organometallic Reagents;Organozinc Halides;Rieke and Organozinc Reagents
Mol File:131379-16-3.mol
4-(Ethoxycarbonyl)phenylzinc iodide Structure
4-(Ethoxycarbonyl)phenylzinc iodide Chemical Properties
density 1.018 g/mL at 25 °C
Fp 1 °F
storage temp. 2-8°C
Water Solubility Reacts with water.
Sensitive Air Sensitive
InChI1S/C9H9O2.HI.Zn/c1-2-11-9(10)8-6-4-3-5-7-8;;/h4-7H,2H2,1H3;1H;/q;;+1/p-1
InChIKeyQKMCGFIQAJUQIL-UHFFFAOYSA-M
SMILESCCOC(=O)c1ccc([Zn]I)cc1
CAS DataBase Reference131379-16-3
Safety Information
Hazard Codes F,Xn
Risk Statements 14-19-22-36/38-40-36/37-11
Safety Statements 16-26-33-36-36/37
RIDADR UN 2056 3/PG 2
WGK Germany 1
HazardClass 4.3
Storage Class3 - Flammable liquids
Hazard ClassificationsAcute Tox. 4 Oral
Carc. 2
Eye Irrit. 2
Flam. Liq. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
4-(Ethoxycarbonyl)phenylzinc iodide Usage And Synthesis
Uses4-(Ethoxycarbonyl)phenylzinc iodide is used as pharmaceutical intermediates.
Uses4-(Ethoxycarbonyl)phenylzinc iodide can be used as:
  • A substrate in the transition metal-catalyzed cross-coupling reactions with unsaturated thioethers and thiomethyl-substituted N-heterocycles.
  • A starting material in the synthesis of indazole derived glucagon receptor antagonists.
  • A substrate in the Pd-catalyzed synthesis of 5-aryl-2-furaldehydes by reacting with 5-bromo-2-furaldehyde.

4-(Ethoxycarbonyl)phenylzinc iodide Preparation Products And Raw materials
Preparation ProductsEthyl 4-(5-formyl-2-furyl)benzoate-->Ethyl 2'-formyl[1,1'-biphenyl]-4-carboxylate
Tag:4-(Ethoxycarbonyl)phenylzinc iodide(131379-16-3) Related Product Information
4-Methylphenylzinc iodide 4-(Ethoxycarbonyl)phenylzinc iodide 3-(Ethoxycarbonyl)phenylzinc iodide Phenylzinc iodide