(-)-1,2(2R,5R)-2,5-(Dimethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate

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(-)-1,2(2R,5R)-2,5-(Dimethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate Basic information
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Product Name:(-)-1,2(2R,5R)-2,5-(Dimethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate
Synonyms:(R,R)-ME-DUPHOS-RH;(S,S)-ME-DUPHOS-RH;(-)-1,2-BIS-((2R,5R)DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) TRIFLATE;(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE;(+)-1,2-BIS((2S,5S)-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) TRIFLATE;(-)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE;(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfon;(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate
CAS:136705-75-4
MF:C27H40F3O3P2RhS
MW:666.52
EINECS:
Product Categories:Chiral Catalysts, Ligands, and Reagents;DuPhos/BPE;Privileged Ligands and Complexes;organometallic complex
Mol File:136705-75-4.mol
(-)-1,2(2R,5R)-2,5-(Dimethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate Structure
(-)-1,2(2R,5R)-2,5-(Dimethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate Chemical Properties
Melting point 136.0-154.7 °C
storage temp. Refrigerator (+4°C)
form crystal
color orange
Sensitive air sensitive, store cold
InChIKeyAKJDLXZYNLUJQJ-KZOFNLLLSA-M
SMILES[Rh+].[O-]S(=O)(=O)C(F)(F)F.C1CC=CCCC=C1.C[C@H]2CC[C@H](C)P2c3ccccc3P4[C@@H](C)CC[C@@H]4C
CAS DataBase Reference136705-75-4
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 24/25-36/37-26
WGK Germany 3
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
ACROS English
(-)-1,2(2R,5R)-2,5-(Dimethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate Usage And Synthesis
ReactionsCatalyst for the enantioselective [2+2+2] cycloaddition of triynes. Reactions of 136705-75-4
Chemical Propertiesorange crystalline powder
UsesDuPhos and BPE Ligands: Highly Efficient Privileged Ligands
(-)-1,2(2R,5R)-2,5-(Dimethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate Preparation Products And Raw materials
Tag:(-)-1,2(2R,5R)-2,5-(Dimethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate(136705-75-4) Related Product Information
(-)-1,2(2R,5R)-2,5-(Dimethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate 1,2-Bis(phosphino)benzene (-)-1,2(2R,5R)-2,5-(Dimethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate (-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene (+)-1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene Benzene Cyclooctane 1,5-Cyclooctadiene