PENTAETHYLENE GLYCOL MONOMETHYL ETHER

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PENTAETHYLENE GLYCOL MONOMETHYL ETHER manufacturers

  • mPEG5-OH
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  • 2026-01-28
  • CAS:23778-52-1
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  • m-PEG5-alcohol
  • m-PEG5-alcohol pictures
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  • 2025-06-07
  • CAS:23778-52-1
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PENTAETHYLENE GLYCOL MONOMETHYL ETHER Basic information
Product Name:PENTAETHYLENE GLYCOL MONOMETHYL ETHER
Synonyms:PENTAETHYLENE GLYCOL MONOMETHYL ETHER;2,5,8,11,14-Pentaoxahexadecan-16-ol;2-[2-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]ethoxy]ethanol;3,6,9,12,15-Pentaoxahexadecanol;PENTAETHYLENE GLYCOL MONOMETHYL ETHER 96+%;POLYETHYLENEGLYCOLMONOMETHYLETHER(N=5);3,6,9,12,15-pentaoxahexadecenol;2,5,8,11,14,17,20,23,26,29,32-Undecaoxatetratriacontan-34-aMine
CAS:23778-52-1
MF:C11H24O6
MW:252.3
EINECS:245-874-6
Product Categories:Ethylene Glycols & Monofunctional Ethylene Glycols;Monofunctional Ethylene Glycols;PEG-COOH;peg
Mol File:23778-52-1.mol
PENTAETHYLENE GLYCOL MONOMETHYL ETHER Structure
PENTAETHYLENE GLYCOL MONOMETHYL ETHER Chemical Properties
Boiling point 110 °C(Press: 0.01 Torr)
density 1.08
refractive index 1.4480 to 1.4520
storage temp. -20°C
form clear liquid
pka14.36±0.10(Predicted)
color Colorless to Light yellow to Light orange
InChIInChI=1S/C11H24O6/c1-13-4-5-15-8-9-17-11-10-16-7-6-14-3-2-12/h12H,2-11H2,1H3
InChIKeySLNYBUIEAMRFSZ-UHFFFAOYSA-N
SMILESC(O)COCCOCCOCCOCCOC
CAS DataBase Reference23778-52-1
EPA Substance Registry System2,5,8,11,14-Pentaoxahexadecan-16-ol (23778-52-1)
Safety Information
Risk Statements 36/37/38
Safety Statements 26-36/37/39
WGK Germany WGK 3
TSCA TSCA listed
HS Code 2909.49.6000
Storage Class10 - Combustible liquids
MSDS Information
PENTAETHYLENE GLYCOL MONOMETHYL ETHER Usage And Synthesis
Descriptionm-PEG5-alcohol is a PEG linker containing a hydroxyl group. The hydroxyl group enables further derivatization or replacement with other reactive functional groups. The hydrophilic PEG spacer increases solubility in aqueous media.
UsesApplications may include: bioconjugation, drug delivery, PEG hydrogel, crosslinker, and surface functionalization
Synthesis
Bis[2-(2-hydroxyethoxy)ethyl] ether

112-60-7

1-Bromo-2-methoxyethane

6482-24-2

PENTAETHYLENE GLYCOL MONOMETHYL ETHER

23778-52-1

The general procedure for the synthesis of pentaethylene glycol monomethyl ether from tetraethylene glycol truncated and 2-bromoethyl methyl ether was as follows: tetraethylene glycol (55 mmol, 10.7 g) was dissolved in 100 mL of tetrahydrofuran (THF), and potassium tert-butoxide (KOtBu, 55 mL, 1.0 M solution in THF) was added to this solution at room temperature. The resulting mixture was stirred at room temperature for 30 min, followed by the slow dropwise addition of 2-bromoethyl methyl ether (55 mmol, 5.17 mL, dissolved in 50 mL THF). The reaction mixture was stirred overnight at room temperature and then extracted with 300 mL of water and 3 x 300 mL of dichloromethane. The organic phases were combined and dried over anhydrous sodium sulfate (Na2SO4). The desiccant was removed by filtration and after evaporation of the solvent, the crude product was purified using silica gel column chromatography (eluent ratio CH2Cl2:CH3OH = 60:140:1) to afford pure pentaethylene glycol monomethyl ether (35% yield).1H NMR (CDCl3) δ 3.75-3.42 (m, 20H, OCH2CH2O), 3.39 (s, 3H MeO).

IC 50PEGs
References[1] Patent: US2005/136031, 2005, A1. Location in patent: Page/Page column 25
Tag:PENTAETHYLENE GLYCOL MONOMETHYL ETHER(23778-52-1) Related Product Information
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