| 中文名称 | Aluminum, [μ4-[1,2,4,5-benzenetetracarboxylato(4-)-κO1:κO2:κO′1:κO′2]]tetra-μ-hydroxytetrahydroxytetra-, hydrate (1:) |
|---|---|
| 中文同义词 | |
| 英文名称 | Aluminum, [μ4-[1,2,4,5-benzenetetracarboxylato(4-)-κO1:κO2:κO′1:κO′2]]tetra-μ-hydroxytetrahydroxytetra-, hydrate (1:) |
| 英文同义词 | Aluminum, [μ4-[1,2,4,5-benzenetetracarboxylato(4-)-κO1:κO2:κO′1:κO′2]]tetra-μ-hydroxytetrahydroxytetra-, hydrate (1:);MIL-120(Al) |
| CAS号 | 1200436-97-0 |
| 分子式 | |
| 分子量 | 0 |
| EINECS号 | |
| 相关类别 | |
| Mol文件 | Mol File |
| 结构式 |
Aluminum, [μ4-[1,2,4,5-benzenetetracarboxylato(4-)-κO1:κO2:κO′1:κO′2]]tetra-μ-hydroxytetrahydroxytetra-, hydrate (1:) 性质
Aluminum, [μ4-[1,2,4,5-benzenetetracarboxylato(4-)-κO1:κO2:κO′1:κO′2]]tetra-μ-hydroxytetrahydroxytetra-, hydrate (1:) 用途与合成方法
| 配位金属 | Al |
| 配体 | 1,2,4,5-苯四甲酸（benzene-1,2,4,5-tetracarboxylicacid） |
| 孔径 | ≈5.4?×4.7? |
| 孔容 | 0.151cm3g?1 |
| 粒径 | MIL-120(Al)-HP为几微米；MIL-120(Al)-AP使用Al(OH)(CH?COO)?时约300nm，使用NaAlO?时约40-50nm |
| 比表面 | ≈373m2/g |
参考文献
[1] A Scalable Robust Microporous Al-MOF for Post-Combustion Carbon Capture. https://doi.org/10.1002/advs.202401070
[2] Occurrence of Uncommon Infinite Chains Consisting of Edge-Sharing Octahedra in a Porous Metal–Organic Framework-Type Aluminum Pyromellitate Al₄(OH)₈[C₁₀O₈H₂] (MIL-120): Synthesis, Structure, and Gas Sorption Properties. https://doi.org/10.1021/cm9023106
[3] Robust Ultramicroporous Metal−Organic Framework with Rich Hydroxyl-Decorated Channel Walls for Highly Selective Noble Gas Separation. https://doi.org/10.1021/acs.jced.0c00323