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TITANIUM PHOSPHIDE

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Products Intro: Product Name:TITANIUM PHOSPHIDE
CAS:12037-65-9
Purity:99.00% Package:25kgs/Drum;200kgs/Drum Remarks:ISO 9001:2015 REACH Approved Manufacturer
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Products Intro: Product Name:TITANIUM PHOSPHIDE
CAS:12037-65-9
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Products Intro: Product Name:Titanium Phosphide
CAS:12037-65-9
Purity:99.99% Package:1000g/RMB 1000;500g/RMB 500;100g/RMB 100
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Products Intro: Product Name:TITANIUM PHOSPHIDE
CAS:12037-65-9
Purity:99.8% Package:20 Remarks:20g
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Products Intro: Product Name:TITANIUM PHOSPHIDE
CAS:12037-65-9
Purity:99% Package:5g;25g;100g;500g
TITANIUM PHOSPHIDE Basic information
Product Name:TITANIUM PHOSPHIDE
Synonyms:TITANIUM PHOSPHIDE;Titanium Phosphide, -100 Mesh;Phosphinidynetitanium(III);Einecs 234-862-6;Titanium phosphide (TiP);phosphanylidynetitanium;TITANIUM PHOSPHIDE ISO 9001:2015 REACH;titanium(III) phosphide
CAS:12037-65-9
MF:PTi
MW:78.84
EINECS:234-862-6
Product Categories:Inorganics
Mol File:12037-65-9.mol
TITANIUM PHOSPHIDE Structure
TITANIUM PHOSPHIDE Chemical Properties
Melting point 1990°C
density 3.95
form gray hexagonal crystals
color gray hexagonal, hexane crystals, crystalline
Water Solubility not attacked by common acids [KIR83]
InChIInChI=1S/P.Ti
InChIKeyADDWXBZCQABCGO-UHFFFAOYSA-N
SMILESP#[Ti]
CAS DataBase Reference12037-65-9
EPA Substance Registry SystemTitanium phosphide (TiP) (12037-65-9)
Safety Information
TSCA TSCA listed
MSDS Information
ProviderLanguage
ALFA English
TITANIUM PHOSPHIDE Usage And Synthesis
Chemical Propertieshard, gray metallic powder(s) with hexagonal structure; prepared by heating phosphine with TiCl4; stable up to 1400°C; finds use as a catalyst in organic reactions [KIR83]
Preparation2 g of Ti filings ground to pinhead size and 4 g of red P are weighed into a small ceramic or sintered clay cylindrical crucible. The materials are degassed by fanning with a high vacuum flame and then sealed (in vacuum) into a quartz pressure tube. The colder half of the tube is heated to 450 °C, while the Ti side is maintained at 950 °C. Two three-day periods are needed for the reaction. After the first period, the tube is slowly cooled for 3-4 hours, and the unreacted P is thus distilled into the cooler section. The grinding is carried out under CSS, which is then removed with alcohol and dried in a vacuum over NaOH at 120-140 ℃. Microscopic examination of the dark-gray metallic product should show no red phosphorus. The phosphorus quantity used for the second reaction stage should again correspond to an atomic ratio of 3 P: 1 Ti. The product treatment after the second three-day heating period is the same as after the first. The resultant phosphide does not correspond entirely to the formula TiP (maximum composition is TiP0 . 9 3 ).
TITANIUM PHOSPHIDE Preparation Products And Raw materials
Tag:TITANIUM PHOSPHIDE(12037-65-9) Related Product Information
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