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Trimethylgermanium chloride

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Trimethylgermanium chloride manufacturers

Trimethylgermanium chloride Basic information
Product Name:Trimethylgermanium chloride
Synonyms:Trimethylgermaniumchloride,min.98%;Germane, chlorotrimethyl-;Trimethylgermyl chloride;TRIMETHYLCHLOROGERMANE;Trimethylchlorogermane, Trimethylgermanium chloride;Trimethylgermanium chloride, min. 98%;Trimethylgermanyl chloride;Chlorotrimethylgermane,98%
CAS:1529-47-1
MF:C3H9ClGe
MW:153.2
EINECS:216-214-4
Product Categories:Chemical Synthesis;Organogermanium;Organometallic Reagents;organogermanium compound;Classes of Metal Compounds;Ge (Germanium) Compounds;Semimetal Compounds
Mol File:1529-47-1.mol
Trimethylgermanium chloride Structure
Trimethylgermanium chloride Chemical Properties
Melting point -13 °C (lit.)
Boiling point 102 °C (lit.)
density 1.24 g/mL at 25 °C (lit.)
refractive index n20/D 1.433(lit.)
Fp 35 °F
storage temp. Flammables area
form liquid
Specific Gravity1.249
color colorless
Water Solubility Immiscible with water.Miscible with ether, tetrahydrofuran, hexane, benzene, dichloromethane and chloroform.
Sensitive Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 3535109
InChI1S/C3H9ClGe/c1-5(2,3)4/h1-3H3
InChIKeyZZBNZZCHSNOXOH-UHFFFAOYSA-N
SMILESC[Ge](C)(C)Cl
CAS DataBase Reference1529-47-1(CAS DataBase Reference)
Safety Information
Hazard Codes F,C
Risk Statements 11-34
Safety Statements 16-26-27-36/37/39-45
RIDADR UN 2924 3/PG 2
WGK Germany 3
8-10-13-21
TSCA No
HS Code 2931.90.9051
HazardClass 3
PackingGroup II
Storage Class3 - Flammable liquids
Hazard ClassificationsFlam. Liq. 2
Skin Corr. 1B
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Trimethylgermanium chloride Usage And Synthesis
Chemical Propertiesclear colorless liquid
UsesTrimethylgermanium chloride is used to prepare trimethyl(2-thienyl)germane. It is also used as alkylating and precursor to prepare Grignard reagent in organic synthesis.
ApplicationTrimethylgermanium chloride can be used as a precursor to germanium-masked dienolates for regioselective C-C bond formation, germanium enolates and α-germanate esters for aldol condensation reactions, Peterson-type reactions, and Claisen rearrangements.
Trimethylgermanium chloride Preparation Products And Raw materials
Tag:Trimethylgermanium chloride(1529-47-1) Related Product Information
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