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| | Benzylmagnesium bromide Basic information |
| | Benzylmagnesium bromide Chemical Properties |
| InChI | InChI=1S/C7H7.BrH.Mg/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1 | | InChIKey | UHPSYHZSDNXIHK-UHFFFAOYSA-M | | SMILES | C(C1C=CC=CC=1)[Mg]Br | | CAS DataBase Reference | 1589-82-8 |
| RIDADR | 2924 | | HazardClass | 3/8 | | PackingGroup | II | | HS Code | 29319090 |
| | Benzylmagnesium bromide Usage And Synthesis |
| Uses | Benzylmagnesium Bromide is mainly used for the formation of diastereomeric o-toluylmethanol via a format reaction. Moreover, benzylmagnesium bromide only generates o-tolylmethanol when used in excess or at higher temperatures[1]. | | Preparation | Benzylmagnesium bromide can be prepared by reacting benzyl bromide with magnesium powder in an anhydrous solvent (such as THF or diethyl ether); the reaction must be carried out under an inert atmosphere (such as nitrogen or argon) to prevent contact with air and moisture. | | storage | Store under inert gas | | References | [1] MARO\VS BELLA. Reaction of selected carbohydrate aldehydes with benzylmagnesium halides: benzyl versus o-tolyl rearrangement.[J]. Beilstein Journal of Organic Chemistry, 2014: 1942-1950. DOI:10.3762/bjoc.10.202. |
| | Benzylmagnesium bromide Preparation Products And Raw materials |
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