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Chloro(cyclopentadienyl)(triphenylphosphine)nickel(II)

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Chloro(cyclopentadienyl)(triphenylphosphine)nickel(II) Basic information
Product Name:Chloro(cyclopentadienyl)(triphenylphosphine)nickel(II)
Synonyms:Nickel, chloro(h5-2,4-cyclopentadien-1-yl)(triphenylphosphine)-;Chloro(cyclopentadienyl)(triphenylphosphine)nickel(Ⅱ) ,97%;Chloro(cyclopentadienyl)(triphenylphosphine)nickel(II),97%;Chloro(cyclopentadienyl)(triphenylphosphine)nickel(Ⅱ);CHLORO(CYCLOPENTADIENYL)(TRIPHENYLPHOSPHINE)NICKEL(II) ISO 9001：2015 REACH;Chloro(cyclopentadienyl)(triphenylphosphine)nickel(II)
CAS:31904-79-7
MF:C23H20ClNiP5*
MW:421.53
EINECS:
Product Categories:Ni;Chemical Synthesis;Catalysis and Inorganic Chemistry
Mol File:31904-79-7.mol
Chloro(cyclopentadienyl)(triphenylphosphine)nickel(II) Structure
Chloro(cyclopentadienyl)(triphenylphosphine)nickel(II) Chemical Properties
Melting point 175 °C (dec.)(lit.)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form solid
InChI1S/C18H15P.C5H5.ClH.Ni/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-5-3-1;;/h1-15H;1-5H;1H;/q;;;+1/p-1
InChIKeyPMWXBCDXVGNPAN-UHFFFAOYSA-M
SMILESCl[Ni].[CH]1[CH][CH][CH][CH]1.c2ccc(cc2)P(c3ccccc3)c4ccccc4
CAS DataBase Reference31904-79-7
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22
Safety Statements 36
WGK Germany 3
HS Code 29319090
Storage Class11 - Combustible Solids
Hazard ClassificationsAcute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
Chloro(cyclopentadienyl)(triphenylphosphine)nickel(II) Usage And Synthesis
Chemical PropertiesBordeaux crystalline powder
UsesReactant for synthesis of:
  • Nickel alkynyl and allenylidene complexes
  • Organometallic complexes for nonlinear optics

Reactant for insertion of decamethylsilicocene in nickel-choline bonds
reaction suitabilitycore: nickel
reagent type: catalyst
Chloro(cyclopentadienyl)(triphenylphosphine)nickel(II) Preparation Products And Raw materials
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