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| | ETHYL 2-METHOXYPHENOXYACETATE Basic information |
| Product Name: | ETHYL 2-METHOXYPHENOXYACETATE | | Synonyms: | Ethyl 2-methoxyphenoxyacetate, 98+%;(o-Methoxyphenoxy)acetic acid ethyl ester;Acetic acid, (2-methoxyphenoxy)-, ethyl ester;Ai3-10576;Einecs 235-977-4;2-(2-Methoxyphenoxy)acetic acid ethyl ester;AKOS B006637;ETHYL 2-METHOXYPHENOXYACETATE | | CAS: | 13078-21-2 | | MF: | C11H14O4 | | MW: | 210.23 | | EINECS: | 235-977-4 | | Product Categories: | | | Mol File: | 13078-21-2.mol |  |
| | ETHYL 2-METHOXYPHENOXYACETATE Chemical Properties |
| Boiling point | 114-117°C 10mm | | density | 1.103 | | refractive index | 1.5130 to 1.5170 | | Fp | 118℃ | | storage temp. | Sealed in dry,Room Temperature | | form | clear liquid | | color | Colorless to Light yellow | | CAS DataBase Reference | 13078-21-2 |
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ALFA
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| | ETHYL 2-METHOXYPHENOXYACETATE Usage And Synthesis |
| Synthesis | The general procedure for the synthesis of ethyl 2-methoxyphenoxyacetate from ethyl bromoacetate and guaiacol was as follows: first, erytftro-1-(3,4-dimethoxyphenyl)-2 -(2-methoxyphenoxy)-1,3-propanediol (2g). The spectral data of the compound were in agreement with literature reports as follows:1H NMR (400 MHz, CDCl3) δ 7.07 (ddd, J = 8.2, 7.2, 1.6 Hz, 1H), 7.02-6.84 (m, 5H), 6.82 (d, J = 8.2 Hz, 1H), 4.98 (bt, J = 4.8 Hz, 1H), 4.16 (ddd, J = 6.0, 4.8, 3.5 Hz, 1H), 3.95-3.90 (m, 1H), 3.87 (s, 3H), 3.86 (s, 6H), 3.66 (ddd, J = 12.0, 7.2, 3.5 Hz, 1H), 2.87 ppm (bs, 1H). hrms (ei) C18H22O6Na [M + Na]+ Calculated value 357.1314, measured value 357.1311. | | References | [1] Organic Letters, 2016, vol. 18, # 19, p. 5166 - 5169
[2] Chemistry - A European Journal, 2011, vol. 17, # 49, p. 13877 - 13882
[3] Green Chemistry, 2017, vol. 19, # 19, p. 4538 - 4543
[4] Journal of Organic Chemistry, 2010, vol. 75, # 19, p. 6549 - 6562
[5] Journal of the American Chemical Society, 2013, vol. 135, # 17, p. 6415 - 6418 |
| | ETHYL 2-METHOXYPHENOXYACETATE Preparation Products And Raw materials |
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