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Energy Chemical |
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(N-Methyl-N-phenylamino)triphenylphosphonium iodide manufacturers
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| | (N-Methyl-N-phenylamino)triphenylphosphonium iodide Basic information |
| Product Name: | (N-Methyl-N-phenylamino)triphenylphosphonium iodide | | Synonyms: | N-METHYLANILINOTRIPHENYLPHOSPHONIUM IODIDE;(N-METHYLPHENYLAMINO)TRIPHENYL- &;Phosphorus(1+), (N-methylbenzenaminato)triphenyl-, iodide, (T-4)-;murahashi's reagent;(N-Methylphenylamino)T;(N-METHYL-N-PHENYLAMINO)-TRIPHENYLPHOSPH;(N-Methylphenylamino)triphenylphosphonium iodide;Murahashi reagent, N-Methylanilinotriphenylphosphonium iodide | | CAS: | 34257-63-1 | | MF: | C25H23INP | | MW: | 495.34 | | EINECS: | | | Product Categories: | Phosphonium Compounds | | Mol File: | 34257-63-1.mol |  |
| | (N-Methyl-N-phenylamino)triphenylphosphonium iodide Chemical Properties |
| Melting point | 238-239°C | | solubility | sol DMF, EtOAc. Behaves as a Wittig-type reagent in terms of solubility. | | form | powder to crystal | | color | White to Yellow to Orange | | CAS DataBase Reference | 34257-63-1(CAS DataBase Reference) |
| Provider | Language |
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ALFA
| English |
| | (N-Methyl-N-phenylamino)triphenylphosphonium iodide Usage And Synthesis |
| Uses | (N-Methyl-N-phenylamino)triphenylphosphonium Iodide is used to synthesis of amines from alcohols; synthesis of unsymmetrical sulfides; synthesis of alkenes from allyl
alcohols; synthesis of 1,3-dienes. | | Preparation | Preparative Method of (N-Methyl-N-phenylamino)triphenylphosphonium Iodide: phenyliminotriphenylphosphorane is reacted with excess Iodomethane at reflux for 2
h. Removal of MeI followed by recrystallization gives a quantitative yield.[1] | | storage | (N-Methyl-N-phenylamino)triphenylphosphonium Iodide stores in sealed bottle on bench. Do not breathe dust, fumes, or vapor.
Avoid contact with skin and eyes. Use in a fume hood. | | References | 1. Tanigawa, Y.; Kanamaru, H.; Sonoda, A.; Murahashi, S-I. JACS 1977, 99, 2361. |
| | (N-Methyl-N-phenylamino)triphenylphosphonium iodide Preparation Products And Raw materials |
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