ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Phosphine ligand >(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE

(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE

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(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE Suppliers list
Company Name: Hebei Chuanghai Biotechnology Co., Ltd
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Products Intro: Product Name:(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
CAS:164858-78-0
Purity:99% Package:1KG;0.00;USD|25KG;0.00;USD
Company Name: Shanghai Daken Advanced Materials Co.,Ltd
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Products Intro: Product Name:(4R)-(+)-4,5-Dihydro-2-[2'-(diphenylphosphino)phenyl]-4-isopropyloxazole
CAS:164858-78-0
Purity:99% Package:1KG,5KG,10KG
Company Name: ATK CHEMICAL COMPANY LIMITED
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Products Intro: Product Name:(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole
CAS:164858-78-0
Package:5MG;10MG;50MG;100MG,1G,5G
Company Name: career henan chemical co
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Products Intro: Product Name:(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
CAS:164858-78-0
Purity:99% Package:3KG;3USD
Company Name: Alchem Pharmtech,Inc.
Tel: 8485655694
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Products Intro: Product Name:(R)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole
CAS:164858-78-0
Purity:97+% Package:1g;10g;100g;;1kg Remarks:Z-61954

(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE manufacturers
(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE Basic information
Reaction
Product Name:(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
Synonyms:(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE 500MG;(4R)-2-[2-(Diphenylphosphino)phenyl]-4,5-dihydro-4-(1-methylethyl)oxazole,99%e.e.;(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline >=97.0% (CHN);(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-ISOPROPYL)-4,5-DIHYDROOXAZOLE;(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE;(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4,5-DIHYDRO-4-ISOPROPYL-OXAZOLE;(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE;(4R)-(+)-4,5-DIHYDRO-2-(2'-(DIPHENYLPHOSPHINO)PHENYL)-4-ISOPROPYLOXAZOLE
CAS:164858-78-0
MF:C24H24NOP
MW:373.43
EINECS:
Product Categories:organophosphine ligand;PHOX Series;Chiral Phosphine
Mol File:164858-78-0.mol
(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE Structure
(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE Chemical Properties
Melting point 85-90 °C
alpha +44° (c 1.4, CHCl3)
Boiling point 492.7±28.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka4.31±0.70(Predicted)
form Powder
color white
Optical Rotation[α]20/D +48±3°, c = 1.4% in chloroform
Sensitive air sensitive
BRN 8156604
InChIInChI=1S/C24H24NOP/c1-18(2)22-17-26-24(25-22)21-15-9-10-16-23(21)27(19-11-5-3-6-12-19)20-13-7-4-8-14-20/h3-16,18,22H,17H2,1-2H3/t22-/m0/s1
InChIKeyOUQSAXROROGQEE-QFIPXVFZSA-N
SMILESO1C[C@@H](C(C)C)N=C1C1=CC=CC=C1P(C1=CC=CC=C1)C1=CC=CC=C1
CAS DataBase Reference164858-78-0
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 37/39-26-24/25
WGK Germany 3
F 10-23
HS Code 29349990
Storage Class11 - Combustible Solids
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE Usage And Synthesis
ReactionChiral ligand used in the asymmetric reduction of highly substituted olefins.
Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to the fact that the catalytic system does not promote double bond isomerization.
Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole.
Decarboxylative allylic alkylation. Reactions of 164858-78-0
Chemical PropertiesWhite crystalline powder
(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE Preparation Products And Raw materials
Tag:(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE(164858-78-0) Related Product Information
Phenethyl alcohol R(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-PHENYL-2-OXAZOLINE (R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE (S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97% R-(+)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE (R)-DM-BINAP (R)-(+)-TolBINAP (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE