ETHYL 2-HYDROXY-5-METHYLBENZOATE

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ETHYL 2-HYDROXY-5-METHYLBENZOATE Basic information
Product Name:ETHYL 2-HYDROXY-5-METHYLBENZOATE
Synonyms:ETHYL 2-HYDROXY-5-METHYLBENZOATE;ETHYL 5-METHYLSALICYLATE;RARECHEM AL BI 0811;2-hydroxy-5-methyl-benzoicaciethylester;Benzoicacid,2-hydroxy-5-methyl-,ethylester;2-hydroxy-5-methyl-benzoic acid ethyl ester;2,5-Cresotic acid ethyl ester;5-Methylsalicylic acid ethyl ester
CAS:34265-58-2
MF:C10H12O3
MW:180.2
EINECS:251-903-3
Product Categories:Aromatic Esters
Mol File:34265-58-2.mol
ETHYL 2-HYDROXY-5-METHYLBENZOATE Structure
ETHYL 2-HYDROXY-5-METHYLBENZOATE Chemical Properties
Melting point 2℃
Boiling point 251 °C(lit.)
density 1.103 g/mL at 25 °C(lit.)
refractive index n20/D 1.522(lit.)
Fp 98 °F
storage temp. RT, stored under nitrogen
pka10.23±0.18(Predicted)
AppearanceLight yellow to yellow Liquid
InChI1S/C10H12O3/c1-3-13-10(12)8-6-7(2)4-5-9(8)11/h4-6,11H,3H2,1-2H3
InChIKeyZGYXABNSOOACGL-UHFFFAOYSA-N
SMILESCCOC(=O)c1cc(C)ccc1O
EPA Substance Registry SystemBenzoic acid, 2-hydroxy-5-methyl-, ethyl ester (34265-58-2)
Safety Information
Hazard Codes Xn
Risk Statements 10-20/21/22-36/37/38
Safety Statements 16-26-36
RIDADR UN 3272 3/PG 3
WGK Germany 3
TSCA TSCA listed
Storage Class3 - Flammable liquids
Hazard ClassificationsAcute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
ETHYL 2-HYDROXY-5-METHYLBENZOATE Usage And Synthesis
UsesEthyl 5-methylsalicylate (ethyl 2-hydroxy-5-methylbenzoate) is a hydroxyl benzoate derivative. One of the methods reported for its synthesis is the esterification of p-cresotinic acid with absolute alcohol. It is formed as an intermediate during the synthesis of 2-propoxy-5-methylbenzoic acid. Ethyl 2-hydroxy-5-methylbenzoate has been isolated as a minor by product in the AlCl3 promoted reaction of 2-methyl furan with ethyl propiolate.
General DescriptionEthyl 5-methylsalicylate (ethyl 2-hydroxy-5-methylbenzoate) is a hydroxyl benzoate derivative. One of the methods reported for its synthesis is the esterification of p-cresotinic acid with absolute alcohol. It is formed as an intermediate during the synthesis of 2-propoxy-5-methylbenzoic acid. Ethyl 2-hydroxy-5-methylbenzoate has been isolated as a minor by product in the AlCl3 promoted reaction of 2-methyl furan with ethyl propiolate.
ETHYL 2-HYDROXY-5-METHYLBENZOATE Preparation Products And Raw materials
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