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Energy Chemical |
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| Company Name: |
Sigma-Aldrich |
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| | LITHIUM TRISIAMYLBOROHYDRIDE Basic information |
| Product Name: | LITHIUM TRISIAMYLBOROHYDRIDE | | Synonyms: | LS-Selectride(R) solution;LS-SELECTRIDE, 1.0M SOLUTION IN TETRAHYD ROFURAN;1MsolutioninTHF;Lithiumtrisamylborohydride;lithium trisiamylborohydride solution;ls-selectride solution;LS-SELECTRIDE(R);LITHIUM TRIISOAMYLBOROHYDRIDE | | CAS: | 60217-34-7 | | MF: | C15H34B.Li | | MW: | 232.18 | | EINECS: | | | Product Categories: | | | Mol File: | 60217-34-7.mol |  |
| | LITHIUM TRISIAMYLBOROHYDRIDE Chemical Properties |
| density | 0.903 g/mL at 25 °C | | Fp | 1 °F | | storage temp. | water-free area | | form | Solution | | color | Clear light brown | | InChI | 1S/C15H34B.Li/c1-10(2)13(7)16(14(8)11(3)4)15(9)12(5)6;/h10-16H,1-9H3;/q-1;+1 | | InChIKey | DGIADQRDWIBVOW-UHFFFAOYSA-N | | SMILES | [Li+].CC(C)C(C)[BH-](C(C)C(C)C)C(C)C(C)C | | CAS DataBase Reference | 60217-34-7 |
| Hazard Codes | F,C | | Risk Statements | 11-14/15-19-22-34-40-37 | | Safety Statements | 16-26-27-36/37/39-45-43 | | RIDADR | UN 3399 4.3/PG 1 | | WGK Germany | 3 | | HS Code | 29310099 | | Storage Class | 4.3 - Hazardous materials which set free flammable gases upon contact with water | | Hazard Classifications | Carc. 2
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3
Water-react 1 |
| | LITHIUM TRISIAMYLBOROHYDRIDE Usage And Synthesis |
| Chemical Properties | CLEAR LIGHT BROWN SOLUTION | | Uses | LS-Selectride is a reducing agent. | | Preparation | LITHIUM TRISIAMYLBOROHYDRIDE can be prepared by the reaction of t-Butyllithium with trisiamylborane, of Lithium Aluminum Hydride with trisiamylborane in the presence of triethylenediamine, or of lithium trimethoxyaluminohydride with trisiamylborane. | | reaction suitability | reagent type: reductant | | storage | air- and moisture-sensitive, flammable liquid. Reacts violently with water. Handle and store under nitrogen or argon. Use in a fume hood. |
| | LITHIUM TRISIAMYLBOROHYDRIDE Preparation Products And Raw materials |
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