4,4-Dimethyl-2-pentyne

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4,4-Dimethyl-2-pentyne Basic information
Product Name:4,4-Dimethyl-2-pentyne
Synonyms:4,4-DIMETHYL-2-PENTYNE;T-BUTYLMETHYLACETYLENE;TIMTEC-BB SBB008719;(tert-C4H9)CequivCCH3;4,4-DIMETHYL-2-PENTYNE, 98%4,4-DIMETHYL-2-PENTYNE, 98%4,4-DIMETHYL-2-PENTYNE, 98%4,4-DIMETHYL-2-PENTYNE, 98%;4,4-Dimethyl-2-pentyne, 97+%;t-Butylmethylacetylene, min. 98%;4,4-DIMETHYL-2-PENTYNE, 98%,
CAS:999-78-0
MF:C7H12
MW:96.17
EINECS:633-707-3
Product Categories:organic compound
Mol File:999-78-0.mol
4,4-Dimethyl-2-pentyne Structure
4,4-Dimethyl-2-pentyne Chemical Properties
Melting point -82.4°C
Boiling point 83°C
density 0.718
refractive index 1.4071
Fp -10°C
form liquid
color colorless
Water Solubility Immiscible with water.
BRN 1733540
Henry's Law Constant3.0×10-4 mol/(m3Pa) at 25℃, Yaws (2003)
CAS DataBase Reference999-78-0
NIST Chemistry Reference2-Pentyne, 4,4-dimethyl-(999-78-0)
Safety Information
Risk Statements 11
Safety Statements 9-16-33
RIDADR 3295
HazardClass 3
PackingGroup II
MSDS Information
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4,4-Dimethyl-2-pentyne English
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4,4-Dimethyl-2-pentyne Usage And Synthesis
Uses4,4-Dimethyl-2-pentyne is used in organometallic reactions for regioselectivity of its insertion into the Pd-C bond of cyclopalladated complexes. It is also used to prepare pyrimidine-dione by reacting with isocyanate in the presence of nickel/ N-heterocyclic carbene.
Synthesis Reference(s)Tetrahedron Letters, 22, p. 2443, 1981 DOI: 10.1016/S0040-4039(01)92928-4
4,4-Dimethyl-2-pentyne Preparation Products And Raw materials
Preparation Products(2,2'-Bipyridine)dichloropalladium(II)-->2-Pentenoic acid, 2,4,4-trimethyl-, (2E)-
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