MOF-74(NI)金属有机骨架
| 中文名称 | MOF-74(NI)金属有机骨架 |
|---|---|
| 中文同义词 | MOF-74(NI)金属有机骨架;双水[Μ-[2,5-二(羟基-ΚO)-1,4-苯二甲酸(4-)-ΚO1:ΚO4]]二镍 |
| 英文名称 | Ni-MOF-74 |
| 英文同义词 | Ni-MOF-74;Ni-DOBDC;MOF-74(Ni);Metal-Organic Framework 74 (Nickel-based) |
| CAS号 | 882977-00-6 |
| 分子式 | C8H4Ni2O8 |
| 分子量 | 345.5 |
| EINECS号 | |
| 相关类别 | MOF |
| Mol文件 | 882977-00-6.mol |
| 结构式 |  |
MOF-74(NI)金属有机骨架 性质
| 配位金属 | Ni |
| 配体 | 2,5-二羟基对苯二甲酸 (CAS:610-92-4) |
| 孔径 | 1.2nm垂直孔道 |
| 孔容 | 0.6cm3/g |
| 粒径 | 3-5um不规则块状颗粒 |
| 比表面 | BET比表面＞700m2/g |
MOF-74(NI)金属有机骨架可用于以下材料制作中：
1) 储气材料（二氧化碳、甲烷）和吸附材料；
2) MOF-74在水溶液中分解，可作为药物载体进行药物吸附和缓释。
参考文献
[1] Hydrogen adsorption in a nickel based coordination polymer with open metal sites in the cylindrical cavities of the desolvated framework. https://doi.org/10.1039/B515434K
[2] Structural transformation of highly active metal-organic framework electrocatalysts during the oxygen evolution reaction. https://doi.org/10.1038/s41560-020-00709-1
[3] Constructing NiCo/Fe3O4 Heteroparticles within MOF-74 for Efficient Oxygen Evolution Reactions. https://doi.org/10.1021/jacs.8b08744
[4] Mixed-Metal Strategy on Metal-Organic Frameworks (MOFs) for Functionalities Expansion: Co Substitution Induces Aerobic Oxidation of Cyclohexene over Inactive Ni-MOF-74. https://doi.org/10.1021/acs.inorgchem.5b01278
[5] Pore-Engineered Metal–Organic Frameworks with Excellent Adsorption of Water and Fluorocarbon Refrigerant for Cooling Applications. https://doi.org/10.1021/jacs.7b04872