(+)-Bis[(R)-1-phenylethyl]amine

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CAS:23294-41-9
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CAS:23294-41-9
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Products Intro: Product Name:(+)-Bis[(R)-1-phenylethyl]amine
CAS:23294-41-9
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Products Intro: Product Name:(+)-Bis[(R)-1-phenylethyl]amine
CAS:23294-41-9
Purity:0.99summer Package:5KG;1KG Remarks:Summer 618
(+)-Bis[(R)-1-phenylethyl]amine Basic information
Product Name:(+)-Bis[(R)-1-phenylethyl]amine
Synonyms:(+)-Bis[(R)-1-phenylethyl]amine, ChiPros;[R-(R*,R*)]-(+)-Bis(α-methylbenzyl)amine;(+)-Bis[(R)-1-phenylethyl]amine;(+)-Bis[(R)-1-phenylethyl]aMine, ChiPros|r, 99%, ee 98+%;(R)-bis((R)-1-phenylethyl)aMine;(+)-Bis[(R)-1-phenylethyl]amine 99%;(+)-BIS (R)-1-PHENYLETHYL!AMINE HYDRO-;(+)-Bis[(R)-1-phenylethyl]amine, 99% (99+% EE/GLC)
CAS:23294-41-9
MF:C16H19N
MW:225.34
EINECS:
Product Categories:
Mol File:23294-41-9.mol
(+)-Bis[(R)-1-phenylethyl]amine Structure
(+)-Bis[(R)-1-phenylethyl]amine Chemical Properties
Melting point ~260 °C
alpha 199 º (NEAT)
Boiling point 86 °C0.05 mm Hg(lit.)
density 0.985 g/mL at 25 °C(lit.)
refractive index n20/D 1.5523(lit.)
Fp >230 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka8.79±0.29(Predicted)
AppearanceColorless to light yellow Liquid
Optical Rotation[α]20/D +199.0°, neat
Water Solubility Insoluble in water.
BRN 3590931
InChI1S/C16H19N/c1-13(15-9-5-3-6-10-15)17-14(2)16-11-7-4-8-12-16/h3-14,17H,1-2H3/t13-,14-/m1/s1
InChIKeyNXLACVVNHYIYJN-ZIAGYGMSSA-N
SMILESC[C@@H](N[C@H](C)c1ccccc1)c2ccccc2
CAS DataBase Reference23294-41-9
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36/37
WGK Germany 3
F 3
Storage Class10 - Combustible liquids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
(+)-Bis[(R)-1-phenylethyl]amine Usage And Synthesis
Uses(+)-Bis[(R)-1-phenylethyl]amine play a very extensive role of making chirally optically active drugs and compounds. Also as intermediates.
Uses(+)-Bis[(R)-1-phenylethyl]amine can be used:
  • In the synthesis ofβ-amino acids.
  • In the preparation of chiral C(19)-C(26) and C(27)-C(32) moieties of scytophycin C.
  • To induce enantioselectivity in the deprotonation of prochiral ketones.
  • As a starting material for the synthesis of chiral phenolate ligands through Mannich condensation reaction.
  • In the synthesis of chiral phosphoramidite ligands.
  • To prepare chiral cyclic isoimidium salts, which are further used to synthesize chiral lactones through Diels-Alder reaction.

(+)-Bis[(R)-1-phenylethyl]amine Preparation Products And Raw materials
Raw materialsEthyl acetate-->Tetrahydrofuran-->Dichloromethane-->Toluene-->Acetonitrile-->Sodium borohydride-->p-Toluenesulfonic acid-->Acetophenone-->HEAVY DISTILLATE-->(R)-(+)-1-Phenylethylamine
Tag:(+)-Bis[(R)-1-phenylethyl]amine(23294-41-9) Related Product Information
Triethanolamine Triallylamine 2-(2-Aminoethylamino)ethanol Diethyltoluenediamine Bis(2-ethylhexyl)amine N,N-Diisopropylethylamine Triethylenediamine Diethylaminoethanol Triethylenetetramine Dibenzylamine (-)-Bis[(S)-1-phenylethyl]amine (+)-Bis[(R)-1-phenylethyl]amine