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Cerium tetrahydroxide

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CAS:12014-56-1
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CAS:12014-56-1
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Cerium tetrahydroxide Basic information
Product Name:Cerium tetrahydroxide
Synonyms:CERIUM (IV) HYDROXIDE;CERIUM (IV) OXIDE HYDRATED;CERIUM (III) HYDROXIDE;CERIC HYDROXIDE;ceric hydroxide,cerium hydroxide;Cerium(IV) hydroxide, min. 85%;Cerium(IV)tetrahydoxide;Cerium hydroxide (ce(OH)4), (beta-4)-
CAS:12014-56-1
MF:CeH4O4
MW:208.14
EINECS:234-599-7
Product Categories:metal hydroxide;Salts;Inorganics;Catalysis and Inorganic Chemistry;Cerium Salts;CeriumMetal and Ceramic Science;Chemical Synthesis
Mol File:12014-56-1.mol
Cerium tetrahydroxide Structure
Cerium tetrahydroxide Chemical Properties
storage temp. Inert atmosphere,Room Temperature
solubility insoluble in H2O; soluble in concentrated acid solutions
form Powder or Lump
color Yellow to pale brown
Odorodorless
Water Solubility insoluble H2O; soluble conc mineral acids [HAW93]
Solubility Product Constant (Ksp)pKsp: 47.7
InChIInChI=1S/Ce.4H2O/h;4*1H2/q+4;;;;/p-4
InChIKeyWTVAYLQYAWAHAX-UHFFFAOYSA-J
SMILES[Ce](O)(O)(O)O
CAS DataBase Reference12014-56-1(CAS DataBase Reference)
EPA Substance Registry SystemCerium hydroxide (Ce(OH)4), (T-4)- (12014-56-1)
Safety Information
Hazard Codes Xi
Risk Statements 36
Safety Statements 26
RIDADR 3262
WGK Germany 3
TSCA TSCA listed
HazardClass 8
PackingGroup III
HS Code 28461020
Storage Class11 - Combustible Solids
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Cerium tetrahydroxide Usage And Synthesis
Chemical PropertiesCerium tetrahydroxide, also known as cerium(IV) hydroxide, is a pale yellow or brownish-yellow powder that is insoluble in water and weak acids but soluble in concentrated acids, forming the corresponding salts. It absorbs CO₂ from the air to form cerium carbonate. It is used to produce cerium salts and as an opacifier to impart a yellow color to glasses and enamels [HAW93].
Cerium tetrahydroxide
CharacteristicsCerium hydroxide exists in two stable forms, namely cerium(III) hydroxide (Ce(OH)₃) and cerium(IV) hydroxide (Ce(OH)₄), which can be interconverted through changes in oxidation state. Cerium(III) hydroxide is a weak base; it is readily soluble in strong acids, forming cerium(III) salts, but insoluble in strong bases. Cerium(IV) hydroxide is amphoteric, with predominantly acidic character; it is soluble in both strong acids, forming cerium(IV) salts, and strong bases, forming cerates.
UsesCerium Hydroxide, also called Cerium Hydrate, is the important raw material for FCC catalyst, auto catalyst, polishing powder, special glass, and water treatment. Cerium is added to the dominant catalyst for the production of styrene from methylbenzene to improve styrene formation. It is used in FCC catalysts containing zeolites to provide both catalytic reactivity in the reactor and thermal stability in the regenerator.
PreparationCerium (IV) hydroxide was prepared by the precipitation of cerium (IV) from an aqueous solution of armonium hexenitratocerate (IV) with aqueous ammonia.
reaction suitabilityreagent type: catalyst
core: cerium
Cerium tetrahydroxide Preparation Products And Raw materials
Raw materialsPotassium permanganate-->Extractant-->rare earth element ore: rare earth metal ore
Tag:Cerium tetrahydroxide(12014-56-1) Related Product Information
NICKEL(II) HYDROXIDE 5-Chlorovaleric acid DL-α-Tocopherol Diphenolic acid CERIUM 4-(Diethylamino)salicylaldehyde GHRP-2 ytterbium trihydroxide Zirconium hydroxide LANTHANUM HYDROXIDE Sodium hydroxide NEODYMIUM HYDROXIDE Calcium hydroxide Cerium dioxide CERIUM Cerium hydroxide (Ce(OH)3) CERIUM (IV) ISOPROPOXIDE CERIUM IV T-BUTOXIDE