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METHYLSULFONYLACETONE

METHYLSULFONYLACETONE Suppliers list
Company Name: J & K SCIENTIFIC LTD.  
Tel: 18210857532 18210857532
Email: jkinfo@jkchemical.com
Company Name: 3B Pharmachem (Wuhan) International Co.,Ltd.  
Tel: 18930552037
Email: 3bsc@sina.com
Company Name: Alfa Aesar  
Tel: 400-6106006
Email: saleschina@alfa-asia.com
Company Name: Energy Chemical  
Tel: 400-0056266
Email: sales8178@energy-chemical.com
Company Name: Wuhan Chemwish Technology Co., Ltd  
Tel: 86-027-67849912
Email: sales@chemwish.com
METHYLSULFONYLACETONE Basic information
Product Name:METHYLSULFONYLACETONE
Synonyms:1-METHANESULPHONYLPROPAN-2-ONE;Methylsulfonylacetone, 98+%;Methanesulfonylacetone, 98+%;METHYLSULFONYLACETONE;METHANESULFONYLACETONE;METHANESULPHONYLACETONE;Methylsulphonylacetone;1-(methylsulphonyl)acetone
CAS:5000-46-4
MF:C4H8O3S
MW:136.17
EINECS:225-665-6
Product Categories:Organic Building Blocks;Sulfones;Sulfur Compounds
Mol File:5000-46-4.mol
METHYLSULFONYLACETONE Structure
METHYLSULFONYLACETONE Chemical Properties
Melting point 48-52 °C (lit.)
Boiling point 300.8±25.0 °C(Predicted)
density 1.208±0.06 g/cm3(Predicted)
Fp >230 °F
storage temp. 2-8°C
form powder or crystals
AppearanceWhite to yellow Solid
Water Solubility Insoluble in water.
BRN 1754113
InChI1S/C4H8O3S/c1-4(5)3-8(2,6)7/h3H2,1-2H3
InChIKeyNWEYGXQKFVGUFR-UHFFFAOYSA-N
SMILESCC(=O)CS(C)(=O)=O
CAS DataBase Reference5000-46-4(CAS DataBase Reference)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
HS Code 29302000
Storage Class11 - Combustible Solids
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
METHYLSULFONYLACETONE Usage And Synthesis
UsesMethylsulfonylacetone is used as reactant for Stereoselective preparation of chiral cyclic ketones. It is used in the Preparation of poly-substituted pyridines. It aids for Gold-catalyzed Friedlander cyclocondensation reaction. It is used as reactant in Radical homoallylation reactions, multicomponent cyclocondensation with aldehydes and aminoazoles.
General DescriptionMethanesulfonylacetone is a sulfonyl group-containing active methylene compound. It can react with Baylis–Hillman acetates in dimethylformamide/potassium carbonate system to form ortho-hydroxyacetophenone derivatives.
METHYLSULFONYLACETONE Preparation Products And Raw materials
Raw materialsmethylsulfinyloxymethane-->1-METHYLTHIO-2-PROPANONE-->Water-->Chloroacetone-->Sodium methanesulfinate-->BROMOACETONE-->Methanesulfonyl chloride-->Acetic acid
Tag:METHYLSULFONYLACETONE(5000-46-4) Related Product Information
METHYLSULFONYLACETONE 4-CHLOROPHENYLSULFONYLACETONE 1-(4'-CHLOROBENZENESULFONYL)-3,3-DIMETHYLBUTANE-2-ONE 2-(P-TOLUENESULFONYL)ACETOPHENONE 2-(PHENYLSULFONYL)ACETOPHENONE 2,5-DIPHENYL-4-HYDROXY-3-OXO-2,3-DIHYDROTHIOPHENE 1,1-DIOXIDE 4-TOLUENESULFONYLACETONE BENZENESULFONYLACETONE 1-(4-TOLUENESULPHONYL)-3,3-DIMETHYLBUTANE-2-ONE 3-((4-CHLOROPHENYL)SULFONYL)-4-ETHOXYBUT-3-EN-2-ONE 4'-METHYL-2(P-TOLYL SULFONYL)ACETOPHENONE 3-CHLORO-1-((4-METHYLPHENYL)SULFONYL)ACETONE 2-METHYLSULFONYLACETOPHENONE 1-(4-CHLOROPHENYL)-2-[(4-CHLOROPHENYL)SULFONYL]-1-ETHANONE 1-(4-METHOXYPHENYL)-2-(PHENYLSULFONYL)-1-ETHANONE 2-PROPANONE, 1-[(4-METHOXYPHENYL)SULFONYL]- 3-Chloro-1-phenylsulfonyl-2-propanone 1-(4-CHLORO-3-METHYLPHENYL)-2-((4-METHYLPHENYL)SULFONYL)ETHAN-1-ONE