Dichlorobis(2-(diphenylphosphino)ethyla&

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Dichlorobis(2-(diphenylphosphino)ethyla& Basic information
Reaction
Product Name:Dichlorobis(2-(diphenylphosphino)ethyla&
Synonyms:Dichlorobis[2-(diphenylphosphino)ethylaMine]rutheniuM(II), Min. 95% (Mixture of isoMers);Dichlorobis[2-(diphenylphosphino)ethylaMine]rutheniuM(II),Min.95%;Dichlorobis(2-(diphenylphosphino)ethylaMine)rutheniuM(II),95%;dichlorobis(2-(diphenylphosphino)ethyla&aMp;Dichlorobis[2-(diphenylphosphino-κP)ethanamine-κN]ruthenium;dichlororuthenium:2-diphenylphosphanylethanamine;2-(diphenylphosphanyl)ethanamine-dichlororuthenium (2:1)
CAS:506417-41-0
MF:2C14H16NP.Cl2Ru
MW:630.499
EINECS:
Product Categories:Ru;organometallic complex
Mol File:506417-41-0.mol
Dichlorobis(2-(diphenylphosphino)ethyla& Structure
Dichlorobis(2-(diphenylphosphino)ethyla& Chemical Properties
Melting point 130-135°C
form Powder
color yellow
InChI1S/2C14H16NP.2ClH.Ru/c2*15-11-12-16(13-7-3-1-4-8-13)14-9-5-2-6-10-14;;;/h2*1-10H,11-12,15H2;2*1H;/q;;;;+2/p-2
InChIKeyBJNVYFXBTNBKRU-UHFFFAOYSA-L
SMILESCl[Ru]Cl.NCCP(c1ccccc1)c2ccccc2.NCCP(c3ccccc3)c4ccccc4
CAS DataBase Reference506417-41-0
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
HS Code 28439090
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
Dichlorobis(2-(diphenylphosphino)ethyla& Usage And Synthesis
ReactionEfficient catalyst for the dihydrogen reduction of carboxylic esters and amides to alcohols. Reactions of 506417-41-0
UsesCatalyst for:
  • Synthesis of long chain linear fatty acid esters
  • Preparation of ruthenium borohydride complexes for use in hydrogenation reactions
  • Dehydrogenation of ammonia boranes
  • Chemoselective reduction of carboxylic esters
  • Synthesis of ruthenium beta-aminophosphine hydrido/chloro complexes with catalytic activities
reaction suitabilitycore: ruthenium
reagent type: catalyst
Dichlorobis(2-(diphenylphosphino)ethyla& Preparation Products And Raw materials
Raw materialsRuthenium, dichlorotris(triphenylphosphine)-, (SP-5-21)--->2-(Diphenylphosphino)ethylamine
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