1H-Indole-6-carboxylicacid,hydrazide(9CI)

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1H-Indole-6-carboxylicacid,hydrazide(9CI) Basic information
Product Name:1H-Indole-6-carboxylicacid,hydrazide(9CI)
Synonyms:1H-Indole-6-carboxylicacid,hydrazide(9CI);1H-Indole-6-carboxylic acid, hydrazide;1H-Indole-6-carbohydrazide;indole-6-carbohydrazide
CAS:851211-74-0
MF:C9H9N3O
MW:175.19
EINECS:
Product Categories:HYDRAZINE
Mol File:851211-74-0.mol
1H-Indole-6-carboxylicacid,hydrazide(9CI) Structure
1H-Indole-6-carboxylicacid,hydrazide(9CI) Chemical Properties
density 1.353±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka12.95±0.30(Predicted)
Safety Information
HS Code 2933998090
MSDS Information
1H-Indole-6-carboxylicacid,hydrazide(9CI) Usage And Synthesis
Synthesis
Methyl indole-6-carboxylate

50820-65-0

1H-Indole-6-carboxylicacid,hydrazide(9CI)

851211-74-0

GENERAL PROCEDURE: Methyl indole-6-carboxylate (5 mmol) was slowly added to hydrazine hydrate (3 mL) at room temperature. Subsequently, the reaction mixture was subjected to microwave irradiation at 300 W power for 5-8 min. The reaction process was monitored in real time by thin layer chromatography (TLC). After the reaction was complete, the mixture was cooled to room temperature and the intermediate 1H-indole-6-carboxylic acid hydrazine was precipitated in 83-98% yield.

References[1] Journal of Chemical Research, 2015, vol. 39, # 5, p. 296 - 299
1H-Indole-6-carboxylicacid,hydrazide(9CI) Preparation Products And Raw materials
Raw materialsMethyl indole-6-carboxylate
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