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cis-3-Hexenyl tiglate

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cis-3-Hexenyl tiglate Basic information
Product Name:cis-3-Hexenyl tiglate
Synonyms:2-methyl-,3-hexenylester,(E,Z)-2-Butenoicacid;cis-3-hexenyl-2-methyl-trans-2-butenoate;cis-Hex-3-ene-1-yltrans-2-methyl-2-butenoate;(Z)-3-hexenyl 2-methylcrotonate;CIS-3-HEXENYL TIGLATE 97+%;2-Butenoic acid, 2-methyl-, (3Z)-3-hexenyl ester, (2E)-;(Z)-3-Hexenyl-2-methylcrotonat;2-methyl-,3-hexenylester,(e,z)-2-butenoicaci
CAS:67883-79-8
MF:C11H18O2
MW:182.26
EINECS:267-554-5
Product Categories:Alphabetical Listings;Flavors and Fragrances;G-H
Mol File:67883-79-8.mol
cis-3-Hexenyl tiglate Structure
cis-3-Hexenyl tiglate Chemical Properties
Boiling point 105 °C5 mm Hg(lit.)
density 0.951 g/mL at 25 °C(lit.)
refractive index n20/D 1.46(lit.)
FEMA 3931 | CIS-3-HEXENYL TIGLATE
Fp 204 °F
storage temp. Store at room temperature
solubility Almost insoluble in water, soluble in alcohol and oils
form clear liquid
color Colorless to Almost colorless
Odorat 10.00 % in propylene glycol. green vegetable green banana earthy cortex herbal
Odor Typegreen
JECFA Number1277
Cosmetics Ingredients FunctionsPERFUMING
LogP4.20
CAS DataBase Reference67883-79-8(CAS DataBase Reference)
EPA Substance Registry System2-Butenoic acid, 2-methyl-, (3Z)-3-hexenyl ester, (2E)- (67883-79-8)
Safety Information
Hazard Codes Xi
Risk Statements 38
Safety Statements 37
WGK Germany 2
RTECS EM9253500
TSCA TSCA listed
HS Code 29161900
MSDS Information
ProviderLanguage
SigmaAldrich English
cis-3-Hexenyl tiglate Usage And Synthesis
Chemical Properties(Z)-3-Hexenyl (E)-2-methyl 2-butenoate has a fresh, green, floral, fruity odor
Uses Cis-3-Hexenyl tiglate finds a little use in the reconstruction of various essential oils, and as part of the topnote complex in modern, green-herbaceous fragrances and as a fresh topnote element in florals and bouquets. Its aroma differs substantially from that of the saturated ester, which is not at all green but very warm-herbaceous and winey, resembling notes in Roman Chamomile oil. It is, therefore, doubtful if the subject ester will find much use in flavour compositions except as a trace component modifier in certain fruit and vegetable flavour compositions.
Production MethodsCis-3-Hexenyl tiglate is produced from cis-3-Hexenol and Tiglic acid by direct esterification.
Aroma threshold valuesAroma characteristics at 1.0%: green, earthy vegetative with mushroom and radish nuances
Taste threshold valuesTaste characteristics at 1 to 5 ppm: green vegetative mushroom with herbaceous and fatty nuances.
cis-3-Hexenyl tiglate Preparation Products And Raw materials
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