(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine

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(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine Basic information
Reaction
Product Name:(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine
Synonyms:(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine;(4S,5S)-2-Chloro-3,4-dimethyl-2,5-phenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers);(4S,5S)-2-Chloro-3,4-dimethyl-2,5-diphenyl-1-oxa-3-aza-2-silacyclopentane ;(4S,5S)-2-CHLORO-3,4-DIMETHYL-2,5-DIPHENYL-1-OXA-3-AZA-2-SILACYCLOPENTANE,MIN.98%(~2:1MIXTUREOFDIASTEREOMERS);(2S,4S)-2-chloro-3,4-dimethyl-2,5-diphenyl-1,3,2-oxazasilolidine;1-Oxa-3-aza-2-silacyclopentane, 2-chloro-3,4-dimethyl-2,5-diphenyl-, (4S,5S)-;(4S)-2-chloro-3,4-dimethyl-2,5-diphenyl-1,3,2-oxazasilolidine
CAS:680592-40-9
MF:C16H18ClNOSi
MW:303.86
EINECS:
Product Categories:organosilicon compounds
Mol File:680592-40-9.mol
(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine Structure
(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine Chemical Properties
Boiling point 358.9±45.0 °C(Predicted)
density 1.146 g/mL at 25 °C
Fp >110℃
pka3.53±0.60(Predicted)
Specific Gravity1.016
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
Sensitive moisture sensitive, store cold
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36/37/39
WGK Germany 3
MSDS Information
(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine Usage And Synthesis
Reaction
  1. Reagent used in the enantioselective Friedel-Crafts alkylations with benzoylhydrazones.
  2. Reagent used in highly enantioselective [3+2] acylhydrazone-enol ether cycloadditions.
Reactions of 680592-40-9
(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine Preparation Products And Raw materials
Tag:(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine(680592-40-9) Related Product Information
(1S,2S)-(+)-PSEUDOEPHEDRINE-D3 HCL (N-METHYL-D3) Norpseudoephedrine hydrochloride (s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine Dimethylaminomethylethoxysilane (s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE