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1,2-Epoxyhexane

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1,2-Epoxyhexane manufacturers

1,2-Epoxyhexane Basic information
Product Name:1,2-Epoxyhexane
Synonyms:BUTYLOXIRAN;BUTYLOXIRANE;1,2-HEXYLENE OXIDE;1,2-EPOXYHEXAN;1,2-EPOXYHEXANE;1,2-Hexene oxide;1,2-hexeneoxide;1-Hexene epoxide
CAS:1436-34-6
MF:C6H12O
MW:100.16
EINECS:215-864-6
Product Categories:Oxiranes;Simple 3-Membered Ring Compounds
Mol File:1436-34-6.mol
1,2-Epoxyhexane Structure
1,2-Epoxyhexane Chemical Properties
Melting point 94°C
Boiling point 120 °C
density 0.83
refractive index 1.41
Fp 15 °C
storage temp. 2-8°C
solubility Difficult to mix.
form clear liquid
color Colorless to Light yellow
Specific Gravity0.831
BRN 102568
InChIInChI=1S/C6H12O/c1-2-3-4-6-5-7-6/h6H,2-5H2,1H3
InChIKeyWHNBDXQTMPYBAT-UHFFFAOYSA-N
SMILESO1CC1CCCC
LogP1.950
CAS DataBase Reference1436-34-6(CAS DataBase Reference)
EPA Substance Registry SystemOxirane, butyl- (1436-34-6)
Safety Information
Hazard Codes F,Xn
Risk Statements 11-22-36/37/38
Safety Statements 26
RIDADR UN 1993 3/PG 2
WGK Germany 3
RTECS MO3630000
F 10-21
HazardClass 3
PackingGroup III
HS Code 29109000
Storage Class3 - Flammable liquids
Hazard ClassificationsAcute Tox. 4 Oral
Eye Irrit. 2
Flam. Liq. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
1,2-Epoxyhexane Usage And Synthesis
Chemical Propertiesclear colorless liquid
Uses1,2-Epoxyhexane is used as chemical reagent, organic intermediates, fine chemicals, pharmaceutical research and development.
Application1,2-Epoxyhexane could used as a passivating agent for core–shell aluminum nanoparticles with very high active aluminum content[1].
SynthesisA method for preparing 1,2-epoxyhexane using a fixed-bed microchannel reaction device is as follows: dissolve 1-hexene in a solvent to prepare a 1-hexene solution, and then dissolve an oxidizing reagent in the solvent to prepare an oxidizing reagent solution. Add the solid catalyst into the fixed-bed microchannel reaction device. Pump the 1-hexene and oxidizing reagent solution configured above into the fixed-bed microchannel reaction device respectively, maintain the reaction residence time for 8-25 minutes, and the upper organic phase enters the continuous centrifuge. The product is obtained after continuous water washing.
storageKeep container tightly closed. Store away from oxidizing agents.
Purification MethodsPurify it by fractional distillation through a 2ft helices-packed column at atmospheric pressure in a N2 atmosphere. [Pasto & Cumbo J Org Chem 30 1271 1965, Howarth et al. J Chem Soc 2433 1927, 13C NMR Davies & Witham J Chem Soc Perkin Trans 2 861 1975, Beilstein 17/1 V 103.]
References[1] Paul A. Jelliss . “The use of 1,2-epoxyhexane as a passivating agent for core–shell aluminum nanoparticles with very high active aluminum content.” Solid State Sciences 23 (2013): Pages 8-12.
Tag:1,2-Epoxyhexane(1436-34-6) Related Product Information
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