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Rhenium pentacarbonyl bromide

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Rhenium pentacarbonyl bromide Basic information
Product Name:Rhenium pentacarbonyl bromide
Synonyms:BROMOPENTACARBONYLRHENIUM;Rhenium, bromopentacarbonyl-;Rheniumpentacarbonylbromide,98%;bromopentacarbonylrhenium(i);PENTACARBONYLBROMORHENIUM (I);Re(CO)5Br;Rhenium, bromopentacarbonyl-, (OC-6-22)-;Rhenium,bromopentacarbonyl-(OC-6-22)-
CAS:14220-21-4
MF:C5HBrO5Re
MW:407.17
EINECS:238-084-8
Product Categories:metal carbonyl complexes
Mol File:14220-21-4.mol
Rhenium pentacarbonyl bromide Structure
Rhenium pentacarbonyl bromide Chemical Properties
Melting point 90°C (subl.)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystal
color off-white
Water Solubility Insoluble in water.
Sensitive Moisture Sensitive
InChI1S/5CO.BrH.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
InChIKeyNWJBOTGGBYFKEJ-UHFFFAOYSA-M
SMILESBr[Re].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
CAS DataBase Reference14220-21-4
Safety Information
Hazard Codes T
Risk Statements 23/24/25-36/37/38
Safety Statements 26-28-36/37/39-45
RIDADR UN 3288 6.1/PG 3
WGK Germany 3
HazardClass 6.1
PackingGroup II
HS Code 29310099
Storage Class6.1D - Non-combustible acute toxic Cat.3
toxic hazardous materials or hazardous materials causing chronic effects
Hazard ClassificationsAcute Tox. 3 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Rhenium pentacarbonyl bromide Usage And Synthesis
Chemical PropertiesOff-white crystalline powder
UsesThis is used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands and also to prepare [3]-ferrocenophane complexes. The starting material for rhenium-polypyridine complexes that have potential applications in catalysis and solar energy conversion.
reaction suitabilitycore: rhenium
reagent type: catalyst
Rhenium pentacarbonyl bromide Preparation Products And Raw materials
Preparation ProductsRhenium pentacarbonyl chloride
Tag:Rhenium pentacarbonyl bromide(14220-21-4) Related Product Information
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