| Company Name: |
Sigma-Aldrich |
| Tel: |
021-61415566 800-8193336 |
| Email: |
orderCN@merckgroup.com |
| Company Name: |
Energy Chemical |
| Tel: |
400-0056266 |
| Email: |
marketing1@energy-chemical.com |
|
| | N-(TRIPHENYLPHOSPHORANYLIDENE)-1H-BENZOTRIAZOLE-1-METHANAMINE Basic information |
| Product Name: | N-(TRIPHENYLPHOSPHORANYLIDENE)-1H-BENZOTRIAZOLE-1-METHANAMINE | | Synonyms: | N-(TRIPHENYLPHOSPHORANYLIDENE)-1H-BENZOTRIAZOLE-1-METHANAMINE;N-(triphenylphosphoranylidene)-1H-benzo-triazole-;1-[[(Triphenylphosphoranylidene)amino]methyl]benzotriazole;benzotriazol-1-ylmethylimino(triphenyl)-$l^{5}-phosphane;N-(Triphenylphosphoranylidene)-1H-benzotriazole-1-MethanaMine,90%;1H-Benzotriazole-1-methanamine, N-(triphenylphosphoranylidene)-;N-(Triphenylphosphoranylidene)-1H-benzotriazole-1-methanamine 90%;benzotriazol-1-ylmethylimino(triphenyl)-λsup5sup-phosphane | | CAS: | 124316-00-3 | | MF: | C25H21N4P | | MW: | 408.43 | | EINECS: | | | Product Categories: | C-C Bond Formation;Others;Synthetic Reagents | | Mol File: | 124316-00-3.mol |  |
| | N-(TRIPHENYLPHOSPHORANYLIDENE)-1H-BENZOTRIAZOLE-1-METHANAMINE Chemical Properties |
| Melting point | 116-122 °C (lit.) | | InChI | 1S/C25H21N4P/c1-4-12-21(13-5-1)30(22-14-6-2-7-15-22,23-16-8-3-9-17-23)26-20-29-25-19-11-10-18-24(25)27-28-29/h1-19H,20H2 | | InChIKey | IOSUDUVEOWKKBL-UHFFFAOYSA-N | | SMILES | C(N=P(c1ccccc1)(c2ccccc2)c3ccccc3)n4nnc5ccccc45 |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36 | | WGK Germany | 3 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | N-(TRIPHENYLPHOSPHORANYLIDENE)-1H-BENZOTRIAZOLE-1-METHANAMINE Usage And Synthesis |
| Uses | Reactant for:
- Grignard reaction
- Preparation of N,N-Bis(but-3-enyl)amines via aza-Wittig reaction with aldehydes, followed by a double Grignard reaction with allylmagnesium bromide
- Organic synthesis of N-alkyliminophosphoranes and a-functionalized N-alkyliminophosphoranes
| | reaction suitability | reaction type: C-C Bond Formation |
| | N-(TRIPHENYLPHOSPHORANYLIDENE)-1H-BENZOTRIAZOLE-1-METHANAMINE Preparation Products And Raw materials |
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