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| | 1-Amino-1,2,4-triazole Basic information |
| Product Name: | 1-Amino-1,2,4-triazole | | Synonyms: | 1H-1,2,3-TRIAZOL-1-AMIN;[1,2,3]Triazol-1-ylamine;triazol-1-amine;1-Amino-1,2,3-triazole;1-Amino-1,2,4-triazole | | CAS: | 584-14-5 | | MF: | C2H4N4 | | MW: | 84.08 | | EINECS: | | | Product Categories: | | | Mol File: | Mol File |  |
| | 1-Amino-1,2,4-triazole Chemical Properties |
| Melting point | 49-50 °C | | Boiling point | 244.9±23.0 °C(Predicted) | | density | 1.59±0.1 g/cm3(Predicted) | | storage temp. | Keep in dark place,Inert atmosphere,Room temperature | | pka | -0.19±0.70(Predicted) | | Appearance | Light yellow to brown Liquid |
| | 1-Amino-1,2,4-triazole Usage And Synthesis |
| Synthesis | Example 7 Synthesis of 1-amino-1,2,3-triazole (III)
813 mg of (1E,2E)-1,2-dihydrazinoethane (I) and 1.0 ml of ethanol were added to the reactor and mixed with stirring at room temperature. To the mixture was added 2.0 g of battery-grade manganese dioxide (Tosoh Corp. product; effective oxygen content ≥ 91%), kept at a constant temperature, and stirring was continued for 2 hours. Subsequently, another 1.0 g of battery grade manganese dioxide was added, the same temperature was maintained and stirring was continued for 5 hours. Upon completion of the reaction, the insoluble material was removed by filtration and the filtrate was concentrated under reduced pressure to give 720 mg (yield: 91%) of 1H-1,2,3-triazol-1-amine (III). The product was analyzed by 1H-NMR (DMSO-d6) and mass spectrometry (FAB+), and the m/e values, boiling point and melting point data were consistent with Example 1. | | References | [1] Patent: US5728841, 1998, A
[2] Patent: US7550601, 2009, B1. Location in patent: Page/Page column 5
[3] Chinese Chemical Letters, 2014, vol. 25, # 2, p. 209 - 211
[4] Journal of Materials Chemistry, 2012, vol. 22, # 2, p. 666 - 674 |
| | 1-Amino-1,2,4-triazole Preparation Products And Raw materials |
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