[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)

[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) Suppliers list

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Products Intro:	Product Name:(1,2-bis(diphenylphosphino)ethane)-dichlorocobalt CAS:18498-01-6

[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) manufacturers

[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) Basic information

Product Name:	[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)
Synonyms:	1,2-Bis(diphenylphosphino)ethanedichlorocobalt(II),Min.97%;1,2-Bis(diphenylphosphino)ethanedichlorocobalt(II),97% (DPPE)CoCl2;Dichloro[ethylenebis[diphenylphosphine]]cobalt;[1,2-BIs(diphenylphosphino);ethane]dichlorocobalt(II);(1,2-bis(diphenylphosphino)ethane)-dichlorocobalt;[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II);[1,2-Bis(diphenylphosphino)ethane]dichlorocobalt(Ⅱ)
CAS:	18498-01-6
MF:	C26H26Cl2CoP2
MW:	530.27
EINECS:
Product Categories:	Co;Catalysis and Inorganic Chemistry;Chemical Synthesis;Cobalt;API intermediates;metal-phosphine complex
Mol File:	18498-01-6.mol

[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) Chemical Properties

Melting point	260 °C (dec.)(lit.)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	Powder
color	green
Water Solubility	Insoluble in water.
Sensitive	Hygroscopic
InChI	1S/C26H24P2.2ClH.Co/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
InChIKey	SYTWXWRJCLAZFP-UHFFFAOYSA-L
SMILES	Cl[Co]Cl.C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4

Safety Information

Hazard Codes	Xn
Risk Statements	20/21/22-36/37/38
Safety Statements	26-37/39
WGK Germany	3
Storage Class	11 - Combustible Solids
Hazard Classifications	Acute Tox. 4 Dermal Acute Tox. 4 Inhalation Acute Tox. 4 Oral Eye Irrit. 2 Skin Irrit. 2 STOT SE 3

MSDS Information

Provider	Language
SigmaAldrich	English

[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) Usage And Synthesis

Reactions	Catalyst used for the hydrovinylation of styrene. Cobalt-catalyzed hydroalkylation of [60] fullerene with active alkyl bromides. Cobalt-catalyzed 1,4-addition of organoboronic acids to activated alkenes.
Uses	Dichloro[bis(1,2-diphenylphosphino)ethane]cobalt(II) is used as a catalyst for regio- and stereoselective intermolecular enzyme coupling, cross-coupling reactions of alkyl halides with aryl Grignard reagents, hydrovinylation of styrene, tandem radical cyclization and cross-coupling, dimethylation, hydrodechlorination and addition reactions.
reaction suitability	core: cobalt reagent type: catalyst

[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) Preparation Products And Raw materials

Tag:[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)(18498-01-6) Related Product Information

ETHANE Dichloroethane Diphenylphosphine Chlorodiphenylphosphine Hexafluoroethane Dichlorodiphenylsilane 1,2-Bis(diphenylphosphino)ethane Dichlorofluoroethane ETHANE-D Cobalt chloride diphenyl(2-phosphinoethyl)phosphine 1,2-BIS(PHENYLPHOSPHINO)ETHANE [1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)