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| | DIETHYLALUMINUM CYANIDE SOLUTION Basic information |
| | DIETHYLALUMINUM CYANIDE SOLUTION Chemical Properties |
| Boiling point | 150 °C(Press: 0.07 Torr) | | density | 0.87 g/mL at 20 °C | | Fp | 45 °F | | solubility | solution in benzene, toluene, diisopropyl ether. | | form | syrup | | color | colorless | | BRN | 3587410 |
| | DIETHYLALUMINUM CYANIDE SOLUTION Usage And Synthesis |
| Uses | DIETHYLALUMINUM CYANIDE SOLUTION Reagents used to hydrocyanate side chain ketones directed by aryl sulfinyl groups.1 | | Application | Diethylaluminum Cyanide is used for hydrocyanation of α,β-unsaturated ketones;[1] preparation of α-cyanohydrins from carbonyl compounds.[2] | | Preparation | Diethylaluminum Cyanide is prepared by reaction of Triethylaluminum with a slight excess of Hydrogen Cyanide below rt[3]. | | storage | Diethylaluminum Cyanide is highly toxic. It can be stored as 1-2 M solutions in benzene, toluene, or
diisopropyl ether. Use in a fume hood. | | References | 1. Nagata, W.; Yoshioka, M.; Hirai, S. JACS 1972, 94, 4635.
2. Agosta, W. C.; Lowrance, W. W., Jr. JOC 1970, 35, 3851.
3. Nagata, W.; Yoshioka, M. OR 1977, 25, 255.
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| | DIETHYLALUMINUM CYANIDE SOLUTION Preparation Products And Raw materials |
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