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| | DIETHYLALUMINUM CYANIDE SOLUTION Basic information |
| | DIETHYLALUMINUM CYANIDE SOLUTION Chemical Properties |
| Boiling point | 150 °C(Press: 0.07 Torr) | | density | 0.87 g/mL at 20 °C | | Fp | 45 °F | | solubility | solution in benzene, toluene, diisopropyl ether. | | form | syrup | | color | colorless | | BRN | 3587410 | | InChI | 1S/2C2H5.CN.Al/c3*1-2;/h2*1H2,2H3;; | | InChIKey | KWMUAEYVIFJZEB-UHFFFAOYSA-N | | SMILES | CC[Al](CC)C#N |
| Hazard Codes | F,T+,N | | Risk Statements | 11-26/27/28-32-38-48/20-50/53-63-65-67 | | Safety Statements | 36/37-45-60-61-62-28-16 | | RIDADR | UN 3123 6.1/PG 1 | | WGK Germany | 2 | | F | 10 | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Acute Tox. 2 Inhalation
Acute Tox. 2 Oral
Acute Tox. 3 Dermal
Aquatic Acute 1
Aquatic Chronic 3
Asp. Tox. 1
Flam. Liq. 2
Repr. 2
Skin Irrit. 2
STOT RE 2 Inhalation
STOT SE 3 |
| | DIETHYLALUMINUM CYANIDE SOLUTION Usage And Synthesis |
| Uses | DIETHYLALUMINUM CYANIDE SOLUTION Reagents used to hydrocyanate side chain ketones directed by aryl sulfinyl groups.1 | | Application | Diethylaluminum Cyanide is used for hydrocyanation of α,β-unsaturated ketones;[1] preparation of α-cyanohydrins from carbonyl compounds.[2] | | Preparation | Diethylaluminum Cyanide is prepared by reaction of Triethylaluminum with a slight excess of Hydrogen Cyanide below rt[3]. | | storage | Diethylaluminum Cyanide is highly toxic. It can be stored as 1-2 M solutions in benzene, toluene, or
diisopropyl ether. Use in a fume hood. | | References | 1. Nagata, W.; Yoshioka, M.; Hirai, S. JACS 1972, 94, 4635.
2. Agosta, W. C.; Lowrance, W. W., Jr. JOC 1970, 35, 3851.
3. Nagata, W.; Yoshioka, M. OR 1977, 25, 255.
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| | DIETHYLALUMINUM CYANIDE SOLUTION Preparation Products And Raw materials |
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