4-Methyl-2-nitroanisole

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4-Methyl-2-nitroanisole Basic information
Product Name:4-Methyl-2-nitroanisole
Synonyms:1-Methoxy-2-nitro-4-methylbenzene;2-Methoxy-5-methyl-1-nitrobenzene;4-Methyl-2-nitroanisole 98+%;4-Methoxy-3-nitrotoluene, 2-Methoxy-5-methylnitrobenzene, 1-Methoxy-4-methyl-2-nitrobenzene;4-METHOXY-3-NITROTOLUENE;4-METHYL-2-NITROANISOLE;4-METHYL-2-NITROPHENOL-METHYL ETHER;P-NITRO-O-CRESYL METHYL ETHER
CAS:119-10-8
MF:C8H9NO3
MW:167.16
EINECS:204-296-4
Product Categories:Intermediates of Dyes and Pigments;Aromatic Ethers;Nitro Compounds;Nitrogen Compounds;Organic Building Blocks;Building Blocks;Chemical Synthesis;Nitro Compounds;Nitrogen Compounds;Organic Building Blocks
Mol File:119-10-8.mol
4-Methyl-2-nitroanisole Structure
4-Methyl-2-nitroanisole Chemical Properties
Melting point 8-9 °C (lit.)
Boiling point 154 °C/14 mmHg (lit.)
density 1.205 g/mL at 25 °C (lit.)
refractive index n20/D 1.557(lit.)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (sparingly), DMSO (Slightly)
form Oil
color Light Yellow to Yellow
Henry's Law Constant7.2×100 mol/(m3Pa) at 25℃, Zhang et al. (2010)
InChI1S/C8H9NO3/c1-6-3-4-8(12-2)7(5-6)9(10)11/h3-5H,1-2H3
InChIKeyLGNMURXRPLMVJI-UHFFFAOYSA-N
SMILESCOc1ccc(C)cc1[N+]([O-])=O
CAS DataBase Reference119-10-8(CAS DataBase Reference)
EPA Substance Registry System4-methyl-2-nitroanisole (119-10-8)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 22-36/37/38
Safety Statements 26-36
WGK Germany 3
TSCA TSCA listed
HS Code 29093090
Storage Class10 - Combustible liquids
Hazard ClassificationsAcute Tox. 4 Oral
MSDS Information
ProviderLanguage
SigmaAldrich English
4-Methyl-2-nitroanisole Usage And Synthesis
Uses4-Methyl-2-nitroanisole may be used in the synthesis of 1-dibromomethyl-4-methoxy-2-nitrobenzene.
General DescriptionNucleophilic substitution reactions of 4-methyl-2-nitroanisole in neat cyclohexylamine and piperidine have been reported.
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