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Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

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Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II) Basic information
Product Name:Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
Synonyms:CHLOROCYCLOPENTADIENYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II);λ2-chloranidylrutheniumbis(ylium);RU(CP)(PPH3)2C;Chlorocyclopentadieny;bis(triphenyL;phosphine)ruthenium(II);Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium(II),99%;Cyclopentadienylbis(triphenylphosphine)ruthenium(II) Chloride
CAS:32993-05-8
MF:C41H35ClP2Ru
MW:726.19
EINECS:
Product Categories:Catalysis and Inorganic Chemistry;Ru Catalysts;Ruthenium;Classes of Metal Compounds;Half Metallocenes;Metallocenes;Ru (Ruthenium) Compounds;Transition Metal Compounds;metallocene;Ru
Mol File:32993-05-8.mol
Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II) Structure
Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II) Chemical Properties
Melting point 135 °C (dec.) (lit.)
storage temp. Inert atmosphere,Room Temperature
form crystal
color orange
Water Solubility soluble
Sensitive Air & Moisture Sensitive
InChIInChI=1S/2C18H15P.C5H5.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-5-3-1;;/h2*1-15H;1-5H;1H;/q;;;;+1/p-1
InChIKeyYUYGUQQDGRTJMA-UHFFFAOYSA-M
SMILESP(C1=CC=CC=C1)(C1C=CC=CC=1)C1=CC=CC=C1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1=CC=CC=C1.[CH]1[CH][CH][CH][CH]1.Cl[Ru] |^1:38,39,40,41,42|
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-37/39-36/37/39-22
WGK Germany 3
TSCA No
HS Code 28439000
Storage Class11 - Combustible Solids
Hazard ClassificationsAcute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II) Usage And Synthesis
Chemical PropertiesOrange powder
UsesCyclopentadienylbis(triphenylphosphine)ruthenium Chloride is used as an efficient transfer hydrogenation catalyst. It is used in the formation of indoles, isoquinolines and quinolines.
reaction suitabilitycore: ruthenium
reagent type: catalyst
Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II) Preparation Products And Raw materials
Raw materialsTriphenylphosphine-->1,3-Cyclopentadiene
Tag:Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)(32993-05-8) Related Product Information
Ruthenium(III) chloride Tris(triphenylphosphine)chlororhodium Dicyclopentadiene Ruthenium 1,3-Cyclopentadiene Triphenylphosphine Methylcyclopentadiene dimer (Formylmethylene)triphenylphosphorane Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II) Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)