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| | Tributyltin trifluoromethanesulfonate Basic information |
| Product Name: | Tributyltin trifluoromethanesulfonate | | Synonyms: | TRI-N-BUTYL(TRIFLUOROMETHANESULFONATE)TIN;TRIBUTYLIN TRIFLATE;TRIBUTYLSTANNYL TRIFLUOROMETHANESULFONATE;TRIBUTYLTIN TRIFLATE;TRIBUTYLTIN TRIFLUOROMETHANESULFONATE, 9 0%;Tributyltin trifluoromethanesulfonate,96%;Tri-n-butyltin trifluoroMethanesulfonate, tech. 90%;Tri-n-butyltin trifluoromethanesulfonate | | CAS: | 68725-14-4 | | MF: | C13H27F3O3SSn | | MW: | 439.12 | | EINECS: | | | Product Categories: | | | Mol File: | 68725-14-4.mol |  |
| | Tributyltin trifluoromethanesulfonate Chemical Properties |
| Melting point | 31 °C | | Boiling point | 56 °C | | Fp | >230 °F | | storage temp. | 2-8°C | | form | Crystals and Chunks | | color | White to light beige | | Hydrolytic Sensitivity | 7: reacts slowly with moisture/water | | Sensitive | Moisture Sensitive | | BRN | 5818090 | | Exposure limits | ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3 | | InChI | 1S/3C4H9.CHF3O3S.Sn/c3*1-3-4-2;2-1(3,4)8(5,6)7;/h3*1,3-4H2,2H3;(H,5,6,7);/q;;;;+1/p-1 | | InChIKey | LIQOILBASIAIQC-UHFFFAOYSA-M | | SMILES | CCCC[Sn](CCCC)(CCCC)OS(=O)(=O)C(F)(F)F |
| Hazard Codes | T,N | | Risk Statements | 21-25-36/38-48/23/25-50/53 | | Safety Statements | 35-36/37/39-45-60-61 | | RIDADR | UN 1760 8/PG 2 | | WGK Germany | 3 | | F | 3-8-10-21 | | TSCA | No | | HazardClass | 6.1(a) | | PackingGroup | II | | HS Code | 29312000 | | Storage Class | 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | | Hazard Classifications | Acute Tox. 3 Oral
Acute Tox. 4 Dermal
Aquatic Acute 1
Aquatic Chronic 1
Eye Irrit. 2
Repr. 1B
Skin Irrit. 2
STOT RE 1 |
| | Tributyltin trifluoromethanesulfonate Usage And Synthesis |
| Chemical Properties | White to light beige crystals and chunks | | Uses | Tri-n-butyltin Trifluoromethanesulfonate is a powerful stannylating reagent. It readily stannylates vinylcuprates and vinylaluminum compounds; catalyzes
hydrostannation of aldehydes and ketones by tin hydrides. | | Preparation | Tribuyltin trifluoromethanesulfonate is prepared from Bis(tri-n-butyltin) Oxide and either Trifluoromethanesulfonic Acid (with subsequent removal of water) or Trifluoromethanesulfonic Anhydride, as in eq 1.
The following procedure is quite convenient: freshly distilled trifluoromethanesulfonic anhydride is caused to react with an
equal molar amount of tributyltin oxide cooled at 20 °C under nitrogen. When the exothermic reaction completely subsides, the
flask is set up for a short-path distillation and the resulting red oil is distilled at about 0.1 mmHg. The distillate is collected
without cooling to prevent crystallization of the product in the condenser. Alternatively, this reagent can be prepared in situ by
the action of trifluoromethanesulfonic acid on Tri-n-butylstannane in benzene or dichloroethane. | | storage | Tribuyltin trifluoromethanesulfonate is deliquescent. Therefore it is best handled as a solution in benzene, ether, or
hexane, stored at room temperature under nitrogen. Solutions can be dried with 4 molecular sieves. As with certain other
trialkyltin electrophiles, tributyltin trifluoromethanesulfonate is foul smelling. The toxicity of this class of compounds has been
described. Use in a fume hood. |
| | Tributyltin trifluoromethanesulfonate Preparation Products And Raw materials |
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