| Company Name: |
Energy Chemical |
| Tel: |
400-0056266 |
| Email: |
sales8178@energy-chemical.com |
| Company Name: |
Sigma-Aldrich |
| Tel: |
021-61415566 800-8193336 |
| Email: |
orderCN@merckgroup.com |
| Company Name: |
LaaJoo |
| Tel: |
021-60702684 18516024827 |
| Email: |
huang.jiayi@sinocompound.com |
|
| | 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Basic information | | Reaction |
| Product Name: | 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE | | Synonyms: | 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE;2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1- &;2,89-Trimethyl-2,5,89-tetraaza-1-phosphabicyclo[3.3.3]undecaneverkadesuperbase;VERKADE SUPERBASE;2,8,9-Trimethyl-1-phospha-2,5,8,9-tetraazabicyclo[3.3.3]undecane;Verkadebase;4,6,11-trimethyl-1,4,6,11-tetraza-5-phosphabicyclo[3.3.3]undecane;2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane, 2,8,9-trimethyl- | | CAS: | 120666-13-9 | | MF: | C9H21N4P | | MW: | 216.26 | | EINECS: | | | Product Categories: | Achiral Phosphine;Alkyl Phosphine;organophosphine ligand | | Mol File: | 120666-13-9.mol | ![2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Structure](CAS/GIF/120666-13-9.gif) |
| | 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Chemical Properties |
| Melting point | 110-115 °C(lit.) | | Boiling point | 263.9±39.0 °C(Predicted) | | pka | 10.43±0.20(Predicted) | | form | solid | | color | white waxy | | Sensitive | moisture sensitive, store cold | | BRN | 4970285 | | InChI | 1S/C9H21N4P/c1-10-4-7-13-8-5-11(2)14(10)12(3)6-9-13/h4-9H2,1-3H3 | | InChIKey | PCYSWBQHCWWSFW-UHFFFAOYSA-N | | SMILES | CN1CCN2CCN(C)P1N(C)CC2 |
| WGK Germany | 3 | | Storage Class | 11 - Combustible Solids |
| | 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Usage And Synthesis |
| Reaction | Exceedingly strong, non-ionic Brønsted and Lewis base useful in a variety of organic transformations.
| | Uses | 2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane (CAS# 120666-13-9) is a useful catalyst for the direct α-arylation of nitriles with aryl chlorides and aryl bromides. It is also used as a catalyst in carbon dioxide reduction to methylamines under metal-free conditions. |
| | 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Preparation Products And Raw materials |
|