| 中文名称 | Zirconium, tetrakis[μ-[5′-(4-carboxyphenyl)-2′,4′,6′-trimethyl[1,1′:3′,1′′-terphenyl]-4,4′′-dicarboxylato(3-)-κO4:κO′4]]tetra-μ3-hydroxytetra-μ3-oxohexa- |
|---|---|
| 中文同义词 | |
| 英文名称 | Zirconium, tetrakis[μ-[5′-(4-carboxyphenyl)-2′,4′,6′-trimethyl[1,1′:3′,1′′-terphenyl]-4,4′′-dicarboxylato(3-)-κO4:κO′4]]tetra-μ3-hydroxytetra-μ3-oxohexa- |
| 英文同义词 | Zirconium, tetrakis[μ-[5′-(4-carboxyphenyl)-2′,4′,6′-trimethyl[1,1′:3′,1′′-terphenyl]-4,4′′-dicarboxylato(3-)-κO4:κO′4]]tetra-μ3-hydroxytetra-μ3-oxohexa-;NU-1200 |
| CAS号 | 2417052-78-7 |
| 分子式 | C120H88O32Zr6 |
| 分子量 | 2589.31 |
| EINECS号 | |
| 相关类别 | |
| Mol文件 | 2417052-78-7.mol |
| 结构式 | ![Zirconium, tetrakis[μ-[5′-(4-carboxyphenyl)-2′,4′,6′-trimethyl[1,1′:3′,1′′-terphenyl]-4,4′′-dicarboxylato(3-)-κO4:κO′4]]tetra-μ3-hydroxytetra-μ3-oxohexa- 结构式](CAS/20250703/GIF/2417052-78-7.gif) |
Zirconium, tetrakis[μ-[5′-(4-carboxyphenyl)-2′,4′,6′-trimethyl[1,1′:3′,1′′-terphenyl]-4,4′′-dicarboxylato(3-)-κO4:κO′4]]tetra-μ3-hydroxytetra-μ3-oxohexa- 性质
Zirconium, tetrakis[μ-[5′-(4-carboxyphenyl)-2′,4′,6′-trimethyl[1,1′:3′,1′′-terphenyl]-4,4′′-dicarboxylato(3-)-κO4:κO′4]]tetra-μ3-hydroxytetra-μ3-oxohexa- 用途与合成方法
| 配位金属 | Zr |
| 配体 | 4,4',4''-(2,4,6-三甲基苯基-1,3,5-三基)三苯甲酸(TMTB) |
| 孔径 | ~1.4nm(微孔)和2.2nm(介孔) |
| 孔容 | 1.10cm3/g |
| 粒径 | 不规则块状 |
| 比表面 | 2620m2/g |
参考文献
[1] Insights into the Structure−Activity Relationship in Aerobic Alcohol Oxidation over a Metal−Organic Framework-Supported Molybdenum(VI) Catalyst. https://doi.org/10.1021/jacs.0c12963