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Potassium (E)-propenyl-1-trifluoroborate

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Potassium (E)-propenyl-1-trifluoroborate Basic information
Product Name:Potassium (E)-propenyl-1-trifluoroborate
Synonyms:PotassiuM (E)-1-propenyl-1-trifluoroborate;potassiuM (E)-trifluoro(prop-1-enyl)borate;Potassium trans-1-propenyltrifluoroborate;(e)-propenyl-1-trifluoroborate;Potassium trifluoro(prop-1-en-1-yl)borate;potassium trifluoro(prop-1-en-1-yl)boranuide;trifluoro-[(E)-prop-1-enyl]boranuide;Potassium (E)-trifluoro(1-propenyl)borate
CAS:804565-39-7
MF:C3H5BF3K
MW:147.9763096
EINECS:
Product Categories:Organic boronic acid;orgnaic boroinic acid
Mol File:804565-39-7.mol
Potassium (E)-propenyl-1-trifluoroborate Structure
Potassium (E)-propenyl-1-trifluoroborate Chemical Properties
Melting point 81-85°C
form solid
InChI1S/C3H5BF3.K/c1-2-3-4(5,6)7;/h2-3H,1H3;/q-1;+1/b3-2+;
InChIKeyRLDWVFWDURMTAV-SQQVDAMQSA-N
SMILES[K+].C\C=C\[B-](F)(F)F
Safety Information
Hazard Codes Xi
Risk Statements 37/38-41
Safety Statements 26-39
WGK Germany 3
Storage Class11 - Combustible Solids
MSDS Information
Potassium (E)-propenyl-1-trifluoroborate Usage And Synthesis
UsesPotassiumtrans-1-propenyltrifluoroborate can be used:
  • As a substrate in the cross-coupling reactions with 2-(chloromethyl)-2,1-borazaronaphthalenes to yield allyl borazaronaphthalenes using a palladium catalyst.
  • In the synthesis of anethole dithiolethione-NH2 (ADT-NH2), which in turn is used to prepare a drug-H2S delivery system.
  • To prepare methyl (E)-2,2-dimethyl-5-(propen-1-yl)-4H-benzo[d][1,3]dioxine-7-carboxylate, a key intermediate for the synthesis of the alkaloid ampullosine.

Potassium (E)-propenyl-1-trifluoroborate Preparation Products And Raw materials
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