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Lithium sulfate

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CAS:10377-48-7
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Lithium sulfate Basic information
Chemical Properties Uses Preparation
Product Name:Lithium sulfate
Synonyms:Dilthium sulfate;Li2SO4;Lithiophor;Lithium sulfate (2:1);Lithium sulfate, alpha;Lithium-Duriles;lithiumsulfate(2:1);lithiumsulfateanhydrous
CAS:10377-48-7
MF:Li2O4S
MW:109.9446
EINECS:233-820-4
Product Categories:Chemical Synthesis;Inorganic Salts;Lithium;Lithium Salts;Materials Science;Metal and Ceramic Science;Synthetic Reagents;LITHIUM COMPOUNDS;LithiumMetal and Ceramic Science;Inorganic Salts;Lithium Salts;Salts;Synthetic Reagents;LithiumProtein Structural Analysis;Optimization Reagents;X-Ray Crystallography;Inorganics
Mol File:10377-48-7.mol
Lithium sulfate Structure
Lithium sulfate Chemical Properties
Melting point 845 °C (lit.)
density 2.22 g/mL at 25 °C (lit.)
refractive index 1.465
storage temp. Inert atmosphere,Room Temperature
solubility absolute ethanol: insoluble(lit.)
form Powder
pka2.08[at 20 ℃]
color White
PH6.0-9.0 (25℃, 2M in H2O)
Water Solubility 25.7 g/100 mL (25 ºC)
Sensitive Hygroscopic
λmaxλ: 260 nm Amax: 0.08
λ: 280 nm Amax: 0.04
Merck 14,5541
Stability:Hygroscopic
CAS DataBase Reference10377-48-7(CAS DataBase Reference)
NIST Chemistry ReferenceLithium sulfate(10377-48-7)
EPA Substance Registry SystemSulfuric acid, dilithium salt (10377-48-7)
Safety Information
Hazard Codes Xn
Risk Statements 22-36/37/38
Safety Statements 26-36/37-24/25
WGK Germany 1
RTECS OJ6419000
TSCA Yes
HS Code 28332990
Toxicitymammal (species unspecified),LD50,intramuscular,560mg/kg (560mg/kg),Farmakologiya i Toksikologiya Vol. 9, Pg. 113, 1974.
MSDS Information
ProviderLanguage
Lithium sulfate English
SigmaAldrich English
ACROS English
ALFA English
Lithium sulfate Usage And Synthesis
Chemical PropertiesLithium sulfate is a colorless monoclinic or hexagonal crystalline solid. It is the lithium salt of sulfuric acid. Although lithium sulfate solution is prepared in a large quantity as an intermediate in the spodumene-sulfuric acid process, the pure compound has only limited industrial use. It is used in small quantities in molten salt baths for the chemical strengthening of glass.
Lithium sulfate
The dissolved lithium sulfate is converted into lithium carbonate by adding sodium carbonate (NaCO3).The sodium replaces the lithium in the sulfate compound.This reaction works this way because sodium is more reactive than lithium.
UsesLithium sulfate is used in making a special type of high strength glass. It also is used in medicine as an antidepressant.
PreparationLithium sulfate is prepared by neutralization of lithium hydroxide or lithium carbonate with sulfuric acid followed by crystallization:
2LiOH + H2SO4 → Li2SO4 + H2O
Li2CO3 + H2SO4 → Li2SO4 + CO2 + H2O
The product obtained from crystallization in a concentrated solution is the monohydrate, Li2SO4•H2O. Anhydrous salt is obtained by heating the monohydrate in a vacuum.
Chemical PropertiesWhite crystalline powder
UsesLithium sulfate, anhydrous is used to treat bipolar disorder, solar panels and the potential for a new class of battery, and used as a catalyst for the elimination reaction.
DefinitionChEBI: Lithium sulfate is a metal sulfate in which the counterion is lithium and the ratio of lithium to sulfate is 2:1. It has a role as an antidepressant. It contains a lithium(1+).
PreparationIndustrially lithium sulfate and its monohydrate are prepared by the same basic procedure. Lithium sulfate monohydrate is isolated by evaporation of a solution of lithium sulfate made by the reaction of sulfuric acid with either lithium hydroxide or lithium carbonate. The lithium sulfate monohydrate may be converted to anhydrous lithium sulfate by drying at slightly over 100°C.
Flammability and ExplosibilityNon flammable
Purification MethodsCrystallise it from H2O (4mL/g) by partial evaporation, and dry it above 130o in vacuo.
Lithium sulfate Preparation Products And Raw materials
Raw materialsSulfuric acid-->Lithium carbonate-->Lithium hydroxide-->Lithium sulfate monohydrate
Tag:Lithium sulfate(10377-48-7) Related Product Information
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