Diphenyl ditelluride

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Diphenyl ditelluride Basic information
Product Name:Diphenyl ditelluride
Synonyms:Ditelluride, diephenyl;Ditelluride, diphenyl;PHENYL DITELLURIDE;Diphenyl perditelluride;Diphenyl pertelluride;Diphenyl ditelluride,97%;Diphenyl ditelluride, 97% 1GR;Diphenyl ditelluride 98%
CAS:32294-60-3
MF:C12H10Te2
MW:409.41
EINECS:250-982-1
Product Categories:Te (Tellurium) Compounds;Classes of Metal Compounds;Semimetal Compounds
Mol File:32294-60-3.mol
Diphenyl ditelluride Structure
Diphenyl ditelluride Chemical Properties
Melting point 65-67 °C (lit.)
storage temp. Store at room temperature
Water Solubility Insoluble in water
solubility sol acetone, chloroform, tetrachloromethane; moderately sol ether; slightly sol ethanol.
form solid
color Light yellow to Yellow to Orange
InChIInChI=1S/C12H10Te2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10H
InChIKeyVRLFOXMNTSYGMX-UHFFFAOYSA-N
SMILESC1(C=CC=CC=1)[Te][Te]C1=CC=CC=C1
Safety Information
Hazard Codes Xn,T,Xi
Risk Statements 20/21/22-36/37/38
Safety Statements 26-36
RIDADR 3282
WGK Germany 3
HazardClass 6.1(b)
PackingGroup III
HS Code 29310099
Storage Class11 - Combustible Solids
Hazard ClassificationsAcute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
Diphenyl ditelluride Usage And Synthesis
Chemical PropertiesOrange to brown crystals and powder
UsesDiphenyl ditelluride may be used in the assay of organolithium and Grignard reagents.
Acquired resistanceDIPHENYL DITELLURIDE is prepared by the action of aryllithium or arylmagnesium halides on tellurium powder followed by oxidation with air or with aqueous potassium ferricyanide. Electron-rich diaryl ditellurides (e.g. bis(2,4-dimethoxyphenyl) ditelluride) are prepared by reaction of the arene with tellurium tetrachloride to give the aryltellurium trichloride followed by reduction with Na2S2O5.
General DescriptionDiphenyl ditelluride (PhTe)2 is a versatile reagent used in the organic synthesis. Neurotoxicity by (PhTe)2 depends on the modulation of signaling pathways initiated at the plasma membrane. Comparative toxicological effects of diphenyl diselenide and (PhTe)2 in mice after in vivo administration has been reported. Teratogenic effects of (PhTe)2 on chicken embryo development has been investigated. The oxidative addition of (PhTe)2 to [Pd(PPh3)4] in dichloromethane is reported to yield [Pd6Cl2Te4(TePh)2(PPh3)6]·1/2CH2Cl2.
storageair stable; unknown toxicity. Use in a fume hood.
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