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| | Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Basic information |
| Product Name: | Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate | | Synonyms: | acetonitrile,(1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate;BIS(ACETONITRILE)(1,5-CYCLOOCTADIENE)RH&;Bis(acetonitrile)(cyclooctadiene)rhodium tetrafluoroborate;Bis(acetonitrile)cycloocta-1,5-dienerhodium tetrafluoroborate;BIS(ACETONITRILE)(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE ISO 9001：2015 REACH;5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE;Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluorob...;Rhodium(1+), bis(acetonitrile)[(1,2,5,6-η)-1,5-cyclooctadiene]-, tetrafluoroborate(1-) (1:1) | | CAS: | 32679-02-0 | | MF: | C12H14BF4N2Rh | | MW: | 375.97 | | EINECS: | 231-291-4 | | Product Categories: | Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhodium | | Mol File: | 32679-02-0.mol |  |
| | Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Chemical Properties |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | solid | | color | yellow | | Sensitive | Air Sensitive | | InChI | 1S/C8H12.2C2H3N.BF4.Rh/c1-2-4-6-8-7-5-3-1;2*1-2-3;2-1(3,4)5;/h1-2,7-8H,3-6H2;2*1H3;;/q;;;-1;+1/b2-1-,8-7-;;;; | | InChIKey | KSMAFOANQHYEJG-SUESZSCISA-N | | SMILES | [Rh+].CC#N.CC#N.F[B-](F)(F)F.C1CC=CCCC=C1 |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26 | | WGK Germany | 3 | | TSCA | No | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Usage And Synthesis |
| Uses | Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate [Rh(cod)(MeCN)2]BF4 may be used as a catalyst for the rhodium(I)-catalyzed silylation of aryl iodides and bromides with tetraethoxysilanes to form aryl silanes such as (4-bromophenyl)triethoxysilane and 4-(triethoxysilyl)acetophenone. | | reaction suitability | core: rhodium
reagent type: catalyst |
| | Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Preparation Products And Raw materials |
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