| Company Name: |
INTATRADE GmbH |
| Tel: |
+49 3493/605464 |
| Email: |
sales@intatrade.de |
| Company Name: |
Energy Chemical |
| Tel: |
400-0056266 |
| Email: |
sales8178@energy-chemical.com |
|
| | Dichlorodicarbonylbis(triphenylphosphine)ruthenium (II) Basic information | | Uses |
| Product Name: | Dichlorodicarbonylbis(triphenylphosphine)ruthenium (II) | | Synonyms: | RUTHENIUM(II)-BIS(TRIPHENYLPHOSPHINE)DICHLOROCARBONYL;DICARBONYLDICHLOROBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II);dicarbonyldichlorobis(triphenylphosphine)-rutheni;dicarbonyldichlorobis(triphenylphosphine)ruthenium;DICARBONYLDICHLOROBIS(TRIPHENYLPHOSPHIN&;Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II),min.98%;Dichlorodicarbonylbis-(triphenylphosphino)-ruthenium;Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II), Ruthenium(II)bis(triphenylphosphine)dichlorocarbonyl | | CAS: | 14564-35-3 | | MF: | C38H30Cl2O2P2Ru | | MW: | 752.57 | | EINECS: | 238-605-9 | | Product Categories: | Ru;metal carbonyl complexes | | Mol File: | 14564-35-3.mol |  |
| | Dichlorodicarbonylbis(triphenylphosphine)ruthenium (II) Chemical Properties |
| Melting point | 230-235°C | | storage temp. | Inert atmosphere,Room Temperature | | form | Powder | | color | white | | InChI | InChI=1S/2C18H15P.2CO.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*1-2;;;/h2*1-15H;;;2*1H;/q;;;;;;+2/p-2 | | InChIKey | PXURRFCLQDNZOY-UHFFFAOYSA-L | | SMILES | P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1C=CC=CC=1)C1=CC=CC=C1.[Ru](Cl)Cl.[O+]#[C-].[O+]#[C-] | | CAS DataBase Reference | 14564-35-3 | | EPA Substance Registry System | Ruthenium, dicarbonyldichlorobis(triphenylphosphine)- (14564-35-3) |
| Hazard Codes | Xn | | Risk Statements | 20/21/22-36/37/38 | | Safety Statements | 22-24/25 | | WGK Germany | 3 | | TSCA | TSCA listed | | HS Code | 28439090 | | Storage Class | 11 - Combustible Solids |
| | Dichlorodicarbonylbis(triphenylphosphine)ruthenium (II) Usage And Synthesis |
| Uses | Dichlorodicarbonylbis(triphenylphosphine)ruthenium exhibits good catalytic performance in the addition reaction of aromatic ketone carbonyl groups with olefin molecules, and can be widely used as a noble metal catalyst in organic synthesis reactions. | | Chemical Properties | white crystals | | reaction suitability | core: ruthenium
reagent type: catalyst | | Synthesis | A certain amount of triphenylphosphine was weighed and added to a 100mL three-necked flask having a quantitative anhydrous ethanol solution, stirred, and heated to boiling, then a certain amount of ruthenium trichloride trihydrate, formaldehyde solution, and potassium hydroxide were added to the three-necked flask in rapid succession. The reaction was heated to reflux (precipitates were produced during the reaction), the reaction was stopped after a period of time, naturally cooled to room temperature and filtered. The filter cake was washed with 95% ethanol, deionized water, 95% ethanol and petroleum ether in sequence, and the precipitate was dried to constant weight to obtain the crude product of dichlorodicarbonylbis(triphenylphosphine)ruthenium, weighed, and the product yield was calculated. |
| | Dichlorodicarbonylbis(triphenylphosphine)ruthenium (II) Preparation Products And Raw materials |
|