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Rhodium(II) trifluoroacetate dimer

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Rhodium(II) trifluoroacetate dimer Basic information
Product Name:Rhodium(II) trifluoroacetate dimer
Synonyms:RHODIUM(II) TRIFLUOROACETATE DIMER;Rhodium(I) trifluoroacetate dimer;Rhodiumtrifluoroacetate;Rhodium(II) trifluoroacetate;Rhodium(II)trifluoroacetatedimer,min.95%;trifluoroacetic acid rhodium(ii) salt dimer;Bis-(trifluoroacetic acid rhodium salt);Rhodium(II) trifluoroacetate dimer, min. 95%
CAS:31126-95-1
MF:C8F12O8Rh2
MW:657.87
EINECS:
Product Categories:Rh;metal acetate salt
Mol File:31126-95-1.mol
Rhodium(II) trifluoroacetate dimer Structure
Rhodium(II) trifluoroacetate dimer Chemical Properties
solubility sol MeCN, DMSO, pyridine; slightly sol dichloromethane, benzene.
form Crystalline Powder
color Green
Stability:hygroscopic
InChIInChI=1S/4C2HF3O2.2Rh/c4*3-2(4,5)1(6)7;;/h4*(H,6,7);;/q;;;;2*+2/p-4
InChIKeyPQEXTYUESSEHKW-UHFFFAOYSA-J
SMILESC(C1=O[Rh+2]234O=C(C(F)(F)F)[O-][Rh+2]2(O=C(C(F)(F)F)[O-]3)(O=C(C(F)(F)F)[O-]4)[O-]1)(F)(F)F
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 3
HS Code 28439000
MSDS Information
ProviderLanguage
SigmaAldrich English
Rhodium(II) trifluoroacetate dimer Usage And Synthesis
Chemical Propertiesgreen
UsesUsed in the preparation of isomerically pure α,β-unsaturated carbonyl compounds and the preparation of building blocks for one-, two-, and three-dimensional molecular solids.
reaction suitabilityreagent type: catalyst
SynthesisRhodium(II) trifluoroacetate dimer is prepared ?from Dirhodium(II) Tetraacetate by ligand displacement in refluxing trifluoroacetic acid containing trifluoroacetic anhydride.
Rhodium(II) trifluoroacetate dimer Preparation Products And Raw materials
Tag:Rhodium(II) trifluoroacetate dimer(31126-95-1) Related Product Information
AMMONIUM TRIFLUOROACETATE Rhodium(II) acetate dimer Trifluoroacetic acid Ethyl trifluoroacetate Trifluoroacetic anhydride Rhodium Silver trifluoroacetate Sodium trifluoroacetate ALKYLKETENE DIMER Fluoroacetic acid Rhodium acetate Rhodium(II) trifluoroacetate dimer

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