methyl [3S-(3alpha,4beta,21beta]-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-9-vinylphorbine-3-propionate

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methyl [3S-(3alpha,4beta,21beta]-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-9-vinylphorbine-3-propionate manufacturers
methyl [3S-(3alpha,4beta,21beta]-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-9-vinylphorbine-3-propionate Basic information
Product Name:methyl [3S-(3alpha,4beta,21beta]-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-9-vinylphorbine-3-propionate
Synonyms:Demagnesia chloric acid -a methyl ester;Chlorophyll Impurity 1;methyl [3S-(3alpha,4beta,21beta]-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-9-vinylphorbine-3-propionate;methylpheophorbide;PHEOPHORBIDEAMETHYLESTER;(3S)-9-Ethenyl-14-ethyl-21α-methoxycarbonyl-4α,8,13,18-tetramethyl-20-oxo-3-phorbinepropanoic acid methyl ester;Methylphaeophorbide a;Methylpheophorbide a
CAS:5594-30-9
MF:C36H38N4O5
MW:606.71
EINECS:227-007-3
Product Categories:
Mol File:5594-30-9.mol
methyl [3S-(3alpha,4beta,21beta]-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-9-vinylphorbine-3-propionate Structure
methyl [3S-(3alpha,4beta,21beta]-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-9-vinylphorbine-3-propionate Chemical Properties
Melting point 226-228 °C
Boiling point 956.2±65.0 °C(Predicted)
density 1.244±0.06 g/cm3(Predicted)
form Solid
color Brown to black
Safety Information
MSDS Information
methyl [3S-(3alpha,4beta,21beta]-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-9-vinylphorbine-3-propionate Usage And Synthesis
UsesMethyl pheophorbide a is a natural product, one of the chlorophyll-a derivatives[1][2].
References[1] F.C. Pennington, et al. Preparation and Properties of Pyrochlorophyll a, Methyl Pyrochlorophyllide a, Pyropheophytin a, and Methyl Pyropheophorbide a Derived from Chlorophyll by Decarbomethoxylation. J. Am. Chem. Soc. 1964, 86, 7, 1418-1426.
[2] ShinOgasawara, et al. C132-Methylation of methyl pheophorbide a and stereoselective preparation of methyl (132R)-methylpyropheophorbide a. Tetrahedron Letters, 2014, 3618-3621.
[3] Ha J Y, et al. Isolation, identification, and apoptosis activity of the photosensitizer methyl pheophorbide A from Perilla frutescens leaves[J]. Applied Biological Chemistry, 2022, 65(1): 52.
methyl [3S-(3alpha,4beta,21beta]-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-9-vinylphorbine-3-propionate Preparation Products And Raw materials
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