| Company Name: |
J & K SCIENTIFIC LTD.
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| Tel: |
18210857532 18210857532 |
| Email: |
jkinfo@jkchemical.com |
| Products Intro: |
Product Name:1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene, min. 98% (S,S)-f-Binaphane
CAS:544461-38-3
Purity:min. 98% Package:100mg;500mg
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| Company Name: |
Shanghai Aladdin Bio-Chem Technology Co.,LTD
|
| Tel: |
400-6206333 13167063860 |
| Email: |
anhua.mao@aladdin-e.com |
| Products Intro: |
Product Name:1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene
CAS:544461-38-3
Purity:≥98% Package:25mg/RMB 774.90;100mg/RMB 2476.90
|
| Company Name: |
Shanghai YuanYe Biotechnology Co., Ltd.
|
| Tel: |
13636370518 |
| Email: |
shyysw007@163.com |
| Products Intro: |
Product Name:(S,S)-F-BINAPHANE
CAS:544461-38-3
Purity:98% Package:100mg Remarks:S53356
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| | (S,S)-F-BINAPHANE Basic information | | Reaction |
| Product Name: | (S,S)-F-BINAPHANE | | Synonyms: | (S,S)-F-BINAPHANE;1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene, Min. 98% (S,S)-f-Binaphane;1,1μ-Bis[(S)-4,5-dihydro-3H-binaphtho[2,1-c:1μ,2μ-e]phosphepino]ferrocene, 1,1μ-Bis[(11bs)-3,5-dihydro-4H-dinaphtho[2,1-c:1μ,2μ-e]phosphenpin-4yl]ferrocene;1,1'-Bis[(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino]ferrocene;1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene (S,S)-f-Binaphane;1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene | | CAS: | 544461-38-3 | | MF: | C54H32FeP2 | | MW: | 798.64 | | EINECS: | | | Product Categories: | | | Mol File: | 544461-38-3.mol |  |
| | (S,S)-F-BINAPHANE Chemical Properties |
| storage temp. | 2-8°C, protect from light, stored under nitrogen | | form | Powder | | color | yellow-brown | | Sensitive | air sensitive, light sensitive |
| | (S,S)-F-BINAPHANE Usage And Synthesis |
| Reaction |
- Ligand for enantioselective Pd-catalyzed hydrogenation of enesulfonamides [5] and cyclic Nsulfonylimines.
- Enantioselective, asymmetric organocatalyst for cycloaddition of allenoates to C60 fullerene (conversion >90%, ee up to 90%)
- Ligand for Iridium-mediated direct asymmetric reductive amination of acetophenone with phenylhydrazide (conversion >99%; yield >94%; ee >94%)
- Ligand used for the palladium-catalyzed, asymmetric, decarboxylative generation and asymmetric allylation of α-imino anions.
- Ligand used in iridium-catalyzed, asymmetric hydrogenation of 6-substituted 3-hydroxypyridinium salts to trans 6-substituted piperidin-3-ols with high enantioselectivities(up to 95% ee).
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| | (S,S)-F-BINAPHANE Preparation Products And Raw materials |
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