O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide

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O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide Basic information
Product Name:O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide
Synonyms:O-ALLYL-N-(9-ANTHRACENYLMETHYL)CINCHONIDINIUM BROMIDE;(-)-O-(9)-ALLYL-N-(9-ANTHRACENYLMETHYL) CINCHONIDINIUM BROMIDE;4-((1R)-((1-(Anthracen-9-yl)but-3-en-2-yl)oxy)((2S)-5-vinylquinuclidin-2-yl)methyl)quinolin-1-ium bromide;O-Allyl-N-[(9-anthracenyl)methyl]cinchonidium bromide;O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide 90%;O-Allyl-1-(anthracen-9-ylmethyl)cinchonidinium bromide;4-[[1-(anthracen-9-ylmethyl)-5-ethenyl-1-azoniabicyclo[2.2.2]octan-2-yl]-prop-2-enoxymethyl]quinoline,bromide;(-)-O-(9)-Allyl-N-(9-anthracenylmethyl) cinchonidiniumbromide
CAS:200132-54-3
MF:C37H37BrN2O
MW:605.61
EINECS:
Product Categories:pharmacetical;Asymmetric Synthesis;Chiral Catalysts, Ligands, and Reagents;Phase Transfer Reaction
Mol File:200132-54-3.mol
O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide Structure
O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide Chemical Properties
Melting point 170 °C (dec.)(lit.)
alpha -340 º (C=0.45 IN CHLOROFORM)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
AppearanceLight yellow to light brown Solid
Optical Rotation[α]20/D 345±30°, c = 0.45 in chloroform
InChIKeyQOWNPAUSLGATNL-JNKXQCINSA-M
SMILES[Br-].[H][C@@]12CC[N+](C[C@@H]1C=C)(Cc3c4ccccc4cc5ccccc35)[C@@]([H])(C2)[C@H](OCC=C)c6ccnc7ccccc67
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide Usage And Synthesis
UsesO-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide can catalyze the asymmetric alkylation of tert-butyl glycinate-benzophenone Schiff base with different arylmethyl bromides in a micellar medium.
General DescriptionO-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide is a cinchona-based chiral phase-transfer catalyst (PTC) that can be used in asymmetric synthesis. It can be prepared from N-(9-anthracenylmethyl)cinchonindinium chloride.
O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide Preparation Products And Raw materials
Tag:O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide(200132-54-3) Related Product Information
Diallylamine Allyl hexanoate Tetrapropylammonium bromide Sodium bromate Ethidium bromide Allyl chloride Allyl bromide Allyl glycidyl ether Sodium allylsulfonate Rocuronium bromide Benzyl bromide C-Anthracen-9-yl-methylamine 9-(Methylaminomethyl)anthracene Methyl bromide Benzyl tripropyl ammonium bromide Benzyltriethylammonium bromide (1-Benzyl-2-piperidinyl)methanol N-Benzylcinchonidinium bromide