Dimethyl (R)-(+)-methylsuccinate

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Dimethyl (R)-(+)-methylsuccinate manufacturers
Dimethyl (R)-(+)-methylsuccinate Basic information
Product Name:Dimethyl (R)-(+)-methylsuccinate
Synonyms:DIMETHYL (R)-(+)-METHYLSUCCINATE;DIMETHYL (R)-(+)-PYROTARTRATE;DIMETHYL-(R)-2-METHYLSUCCINATE;(R)-(+)-METHYLSUCCINIC ACID DIMETHYL ESTER;(R)-(+)-DIMETHYL (R)-METHYLSUCCINATE;(R)-(+)-PYROTARTARIC ACID DIMETHYL ESTER;dimethyl (r)-(+)-pyrotartarate;(R)-(+)-METHYLSUCCINIC ACID DIMETHYL ESTER 98+%
CAS:22644-27-5
MF:C7H12O4
MW:160.17
EINECS:
Product Categories:Chiral Building Blocks;Esters (Chiral);Synthetic Organic Chemistry;Chiral Building Blocks;Esters;Organic Building Blocks
Mol File:22644-27-5.mol
Dimethyl (R)-(+)-methylsuccinate Structure
Dimethyl (R)-(+)-methylsuccinate Chemical Properties
Melting point 140-145 °C (decomp)
Boiling point 80-81 °C12 mm Hg(lit.)
density 1.076 g/mL at 25 °C(lit.)
refractive index n20/D 1.419
Fp 184 °F
storage temp. Sealed in dry,Room Temperature
form liquid
Optical Rotation[α]20/D +4.8°, c = 2.9 in chloroform
BRN 1706307
InChI1S/C7H12O4/c1-5(7(9)11-3)4-6(8)10-2/h5H,4H2,1-3H3/t5-/m1/s1
InChIKeyNFOQJNGQQXICBY-RXMQYKEDSA-N
SMILESCOC(=O)C[C@@H](C)C(=O)OC
LogP0.550 (est)
CAS DataBase Reference22644-27-5(CAS DataBase Reference)
Safety Information
Safety Statements 23-24/25
RIDADR NA 1993 / PGIII
WGK Germany 3
HS Code 2917198090
Storage Class10 - Combustible liquids
MSDS Information
ProviderLanguage
SigmaAldrich English
Dimethyl (R)-(+)-methylsuccinate Usage And Synthesis
Chemical Propertiescolorless liquid
UsesDimethyl (R)-(+)-methylsuccinate can be used in the synthesis of FK-506, a macrolide generally produced by Streptomyces tsukubaensis.
Dimethyl (R)-(+)-methylsuccinate Preparation Products And Raw materials
Raw materialsDimethyl itaconate-->Citraconic acid dimethyl ester-->Methanol-->carbon monoxide-->Itaconic acid-->Hydrogen-->Acetamide
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