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Dichlorotriphenyl bismuth

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Dichlorotriphenyl bismuth Basic information
Product Name:Dichlorotriphenyl bismuth
Synonyms:DICHLOROTRIPHENYLBISMUTH;TRIPHENYLBISMUTH(V) DICHLORIDE;TTIPHENYLBISMUTH DICHLORIDE;Triphenylbismuthine dichloride;dichloro(triphenyl)bismuthorane;Dichlorotriphenylbismuth(V);Dichlorotriphenylbismuthine;Triphenyldichlorobismuth
CAS:594-30-9
MF:C18H15BiCl2
MW:511.2
EINECS:
Product Categories:Semimetal Compounds;Synthetic Organic Chemistry;Bi (Bismuth) Compounds;Classes of Metal Compounds;Hypervalent Bismuth Compounds
Mol File:594-30-9.mol
Dichlorotriphenyl bismuth Structure
Dichlorotriphenyl bismuth Chemical Properties
Melting point 128-142°C
storage temp. Refrigerator
solubility soluble in Tetrahydrofuran
form powder to crystal
color White to Almost white
EPA Substance Registry SystemTriphenylbismuthine dichloride (594-30-9)
Safety Information
Hazard Codes Xi
Risk Statements 20/21/22-36/37/38
Safety Statements 26-36/37/39
HS Code 2931.90.6000
MSDS Information
Dichlorotriphenyl bismuth Usage And Synthesis
Uses Dichlorotriphenyl bismuth is used for phenylation of phenols, ketones and enols, and nitro compounds.
Preparation Dichlorotriphenyl bismuth is easily prepared by oxidation of Triphenylbismuthine either by bubbling Chlorine gas into an ethereal solution of Ph3Bi at 0°C, or by addition of 1 equiv of Sulfuryl Chloride to a solution of Ph3Bi in CH2Cl2 at -78°C. The action of Phenyllithium on Ph3BiCl2 leads to pentaphenylbismuth (mp 77-78 °C). Addition of 1 equiv of a carboxylic or sulfonic acid to Ph5Bi affords compounds of the type Ph4BiX.(Ph4BiOCOCF3: mp 120-132 °C; Ph4BiOTs: mp 155-162 °C).
DefinitionChEBI: Dichloro(triphenyl)bismuthorane is an organobismuth compound. It derives from a hydride of a bismuthorane.
storage Dichlorotriphenyl bismuth is a stable white solid; can be stored in the refrigerator in the absence of moisture.
Dichlorotriphenyl bismuth Preparation Products And Raw materials
Tag:Dichlorotriphenyl bismuth(594-30-9) Related Product Information
Dichlorotriphenylphosphorane Triphenylbismuth carbonate Bis(acetato-o)triphenylbismuth Bismuth Cobalt chloride 2,3,5-Triphenyltetrazolium chloride Bismuth trioxide Chlorodiphenylphosphine Triphenylphosphine Bismuth trichloride Triphenylbismuth Difluoride Benzyltriphenylphosphonium chloride Triphenylbismuth Bismuth trimethyl Dichloro(tri-o-tolyl)bismuth Dichlorotris(4-trifluoromethylphenyl)bismuth Dichlorotris(2-methoxyphenyl)bismuth Dichlorotriphenyl bismuth