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Rhodizonic acid dipotassium salt

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Rhodizonic acid dipotassium salt Basic information
Product Name:Rhodizonic acid dipotassium salt
Synonyms:DIPOTASSIUM RHODIZONATE;POTASSIUM RHODIZONATE;RHODIZONIC ACID POTASSIUM SALT;5-Cyclohexene-1,2,3,4-tetrone,5,6-dihydroxy-,dipotassiumsalt;rhodizonic;5,6-DIHYDROXY-5-CYCLOHEXENE-1,2,3,4-TETRONE DIPOTASSIUM SALT;2,3,4-tetrone,5,6-dihydroxy-5-cyclohexene-dipotassiumsalt;3,4,5,6-tetraoxocyclohexene-1,2-diolate
CAS:13021-40-4
MF:C6H3KO6
MW:210.18
EINECS:235-881-2
Product Categories:Classes of Metal Compounds;K (Potassium) Compounds (excluding simple potassium salts);Typical Metal Compounds
Mol File:13021-40-4.mol
Rhodizonic acid dipotassium salt Structure
Rhodizonic acid dipotassium salt Chemical Properties
Melting point >300 °C (lit.)
Water Solubility Soluble in water
form powder
color dark brown to black
Stability:Stable.
InChI1S/C6H2O6.2K/c7-1-2(8)4(10)6(12)5(11)3(1)9;;/h7-8H;;/q;2*+1/p-2
InChIKeyNEWIILAQDSMNML-UHFFFAOYSA-L
SMILES[K+].[K+].[O-]C1=C([O-])C(=O)C(=O)C(=O)C1=O
CAS DataBase Reference13021-40-4(CAS DataBase Reference)
EPA Substance Registry System5-Cyclohexene-1,2,3,4-tetrone, 5,6-dihydroxy-, dipotassium salt (13021-40-4)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
TSCA TSCA listed
HS Code 2914.69.9000
Storage Class11 - Combustible Solids
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Rhodizonic acid dipotassium salt Usage And Synthesis
Chemical Propertiesviolet to black powder
UsesPotassium rhodizonate is suitable reagent for the preparation of staining solution used in the rhodizonate test for the detection of lead. It is suitable reagent used in the preparation of barium, thallium, ammonium and silver salts rhodizonic acid by metathesis in aqueous solution.
It may be used in the following studies:
  • To cocrystallize plutonium and radium from urine in the plutonium and radium assay of urine.
  • As a dye in the spectrophotometric determination of sulfate ion.
  • To determine the acid dissociation constants of rhodizonic acid by pH potentiometric titration of potassium rhodizonate with standardized HCl.
  • As a staining agent for plagioclase in the petrographic study.
General DescriptionPotassium rhodizonate (3,4,5,6-Tetraoxocyclohexene-1,2-diol dipotassium salt, Rhodizonic acid potassium salt), a benzoquinone derivative, is the potassium salt of rhodizonic acid. Its crystalline structure has been reported and it exhibits space group Fddd. Rhodizonate dianion undergoes various thermal and photochemical reactions with various oxidizing reagents in aqueous solution.
Rhodizonic acid dipotassium salt Preparation Products And Raw materials
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